Optimization of Fluoride Adsorption on Acid Modified Bentonite Clay Using Fixed-Bed Column by Response Surface Method

Using small-scale batch tests, various researchers investigated the adsorptive removal of fluoride using low-cost clay minerals, such as Bentonite. In this study, Column adsorption studies were used to investigate the removal of fluoride from aqueous solution using acid-treated Bentonite (ATB). The effects of initial fluoride concentration, flow rates, and bed depth on fluoride removal efficiency (R) and adsorption capability (qe) in continuous settings were investigated, and the optimal operating condition was determined using central composite design (CCD). The model’s suitability was determined by examining the relationship between experimental and expected response values. The analysis of variance was used to determine the importance of independent variables and their interactions. The optimal values were determined as the initial concentration of 5.51 mg/L, volumetric flow rate of 17.2 mL/min and adsorbent packed-bed depth of 8.88 cm, with % removal of 100, adsorptive capacity of 2.46 mg/g and desirability of 1.0. This output reveals that an acid activation of Bentonite has made the adsorbent successful for field application.

Combining Diffusion, Convection and Absorption: A Pilot Study of Polymethylmethacrylate versus Polysulfone Membranes in the Removal of P-Cresyl Sulfate by Postdilution On-Line Hemodiafiltration

Dialytic clearance of p-cresyl sulfate (pCS) and other protein-bound toxins is limited by diffusive and convective therapies, and only a few studies have examined how to improve their removal by adsorptive membranes. This study tested the hypothesis that high-flux polymethylmethacrylate (PMMA) dialysis membranes with adsorptive capacity increase pCS removal compared to polysulfone membranes, in a postdilution on-line hemodiafiltration (OL-HDF) session. Thirty-five stable hemodialysis patients randomly completed a single study of 4 h OL-HDF with PMMA (BG2.1U, Toray®, Tokyo, Japan) and polysulfone (TS2.1, Toray®) membranes. The primary endpoint was serum pCS reduction ratios (RRs) obtained with each dialyzer. Secondary outcomes included RRs of other solutes such as β2-microglobulin, the convective volume obtained after each dialysis session, and the dialysis dose estimated by ionic dialysance (Kt) and urea kinetics (Kt/V). The RRs for pCS were higher with the PMMA membrane than those obtained with polysulfone membrane (88.9% vs. 58.9%; p < 0.001), whereas the β2-microglobulin RRs (67.5% vs. 81.0%; p < 0.001), Kt (60.2 ± 8.7 vs. 65.5 ± 9.4 L; p = 0.01), Kt/V (1.9 ± 0.4 vs. 2.0 ± 0.5; p = 0.03), and the convection volume (18.8 ± 2.8 vs. 30.3 ± 7.8 L/session; p < 0.001) were significantly higher with polysulfone membrane. In conclusion, pCS removal by OL-HDF was superior with high-flux PMMA membranes, appearing to be a good dialysis strategy for improving dialytic clearance of pCS, enabling an acceptable clearance of β2-microglobulin and small solutes.

Adsorption Behavior of Crystal Violet and Congo Red Dyes on Heat-Treated Brazilian Palygorskite: Kinetic, Isothermal and Thermodynamic Studies

The effect of heat treatment on the adsorptive capacity of a Brazilian palygorskite to remove the dyes crystal violet (CV) and congo red (CR) was investigated. The natural palygorskite was calcined at different temperatures (300, 500 and 700 °C) for 4 h. Changes in the palygorskite structure were evaluated using X-ray diffraction, X-ray fluorescence, thermogravimetric and differential thermal analysis, N2 adsorption/desorption and Fourier transform infrared spectroscopy. The adsorption efficiency of CV and CR was investigated through the effect of initial concentration, contact time, temperature, pH and dosage of adsorbent. The calcination increased the adsorption capacity of palygorskite, and the greatest adsorption capacity of CV and CR dyes occurred in the sample calcined at 700 °C (Pal-700T). The natural and calcined samples at 300 and 500 °C followed the Freundlich isothermal model, while the Pal-700T followed the Langmuir isothermal model. Adsorption kinetics results were well described by the Elovich model. Pal-700T showed better adsorption performance at basic pH, with removal greater than 98%, for both dyes. Pal-700T proved to be a great candidate for removing cationic and anionic dyes present in water.

Use of Reactivated Spent FCC Catalyst as Adsorbent for Lead (II) Ions from Refinery-based Simulated Wastewater

Improper handling of wastewater from various industries causes environmental pollution. Hence, this study involved using a reactivated spent FCC catalyst, a cheap and reliable adsorbent for Pb2+ removal from refinery-based simulated wastewater. In contrast, response surface methodology (RSM) was used to determine the optimum operating condition. The adsorptive capacity of the reactivated spent FCC catalyst was observed using different parameters such as temperature, pH, adsorbent dosage, and contact time. At the end of the study, it was found that the optimum condition for removing Pb2+ was at pH of 7, adsorbent dose of 1.75 g, contact time of 75 mins, and temperature of 117 oC. At this condition, the maximum removal efficiency of Pb2+ was found to be 100 %. A quadratic model equation via central composite design under the RSM was developed to predict the Pb2+ removal from all the input parameters. Based on the F-statistic values, the temperature had the greatest influence on the removal of Pb2+ while adsorbent dosage and contact time were also significant.

Metagenomic Insights Into the Microbial Iron Cycle of Subseafloor Habitats

Microbial iron cycling influences the flux of major nutrients in the environment (e.g., through the adsorptive capacity of iron oxides) and includes biotically induced iron oxidation and reduction processes. The ecological extent of microbial iron cycling is not well understood, even with increased sequencing efforts, in part due to limitations in gene annotation pipelines and limitations in experimental studies linking phenotype to genotype. This is particularly true for the marine subseafloor, which remains undersampled, but represents the largest contiguous habitat on Earth. To address this limitation, we used FeGenie, a database and bioinformatics tool that identifies microbial iron cycling genes and enables the development of testable hypotheses on the biogeochemical cycling of iron. Herein, we survey the microbial iron cycle in diverse subseafloor habitats, including sediment-buried crustal aquifers, as well as surficial and deep sediments. We inferred the genetic potential for iron redox cycling in 32 of the 46 metagenomes included in our analysis, demonstrating the prevalence of these activities across underexplored subseafloor ecosystems. We show that while some processes (e.g., iron uptake and storage, siderophore transport potential, and iron gene regulation) are near-universal, others (e.g., iron reduction/oxidation, siderophore synthesis, and magnetosome formation) are dependent on local redox and nutrient status. Additionally, we detected niche-specific differences in strategies used for dissimilatory iron reduction, suggesting that geochemical constraints likely play an important role in dictating the dominant mechanisms for iron cycling. Overall, our survey advances the known distribution, magnitude, and potential ecological impact of microbe-mediated iron cycling and utilization in sub-benthic ecosystems.

Eichhornia crassipes (Mart.) Solms (natural or carbonized) as biosorbent to remove pollutants in water

The prolific aquatic herb Eichhornia crassipes considered a pest in many countries can cause damage such as obstruction of water flows and impair the locomotion of fishing boats. However, E. crassipes is renewable, inexpensive, and widely available in nature, and its ability to adsorb recalcitrant pollutants with mutagenic and carcinogenic properties, including synthetic dyes and heavy metals, has been extensively studied by the scientific community. This review paper analyzes previous reports concerning the use of E. crassipes (in the natural and carbonized form) as an adsorbent for heavy metal cations and textile dye. The adsorptive capacity of E. crassipes, the best conditions (adsorbent dosage, pH, and temperature) for the removal of these pollutants, the mechanism of adsorption, and the comparison between natural and carbonized forms (advantages and disadvantages) are discussed. All the results revised in this review indicated that the use of E. crassipes (and its carbon derived) as adsorbent is promising and is an excellent material to be applied in the water treatment. It could be used in the actual technologies for the treatment of contaminated water by heavy metals and textile dyes; however, more studies need to be made on scale-up, economy projects, and related issues, to be finally implemented in wastewater treatment plants.

Sensitivity Enhancement of Silver Based Surface Plasmon Resonance Sensor via Graphene-Dielectric Composite Structure

In this paper, a silver based surface plasmon resonance (SPR) sensor with graphene and dielectric layer was presented. The influences of dielectric layer and graphene on sensitivity and other sensing properties were theoretically calculated and then comprehensively discussed. The refractive index sensitivities for composite silver film based SPR sensors with graphene and dielectric layer could be increased by 29% and 288% than that of monolayer silver film based SPR sensor, respectively. Further, the sensitivity could be enhanced by 202% when combining graphene and dielectric layer together. Considering the high adsorptive capacity of graphene for biochemical molecules, the composite silver film with both dielectric layer and graphene would have great potential application in biochemical sensing fields. Further, BSA protein was successfully used to verify the biochemical sensing ability of proposed SPR sensor. The shift of resonance angle is nearly 3.1 folds than that of monolayer silver based SPR sensor.

Treatment of Organic Compounds Resulting from Oil Refineries under Solar Light and Reuse it for Industrial Purpose

This paper was aimed to examine the removal of oil from water by photocatalytic advance oxidation under solar light. A pH of 11 has shown a higher oil removal efficiency. Oil remove efficiency levels at pH 11 have been found 75% within 230 minutes’ oily water effluent, studies have shown that Langmuir isotherm has been the best-fit one of the isotherms for the removal of oil. Data have shown a higher adsorptive capacity. Also we have studied another parameter like (catalyst concentration, initial oil concentration and pH). While the treatment of waste-water is dependent upon a great level of quality for the processed industrial water, the nature of wastes that are added throughout the utilization, and the treatment degree that has been received by the waste-water. Then, the data of the waste-water quality that has been measured rou-tinely and it was reported at the plants of the waste-water treatments are mainly for disposal of the treated effluent or the necessities of the discharge in terms of the gross pollution parameters.