mass transfer coefficients
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Processes ◽  
2021 ◽  
Vol 9 (12) ◽  
pp. 2168
Author(s):  
Timothy A. G. Langrish ◽  
Chao Zhong ◽  
Lizhe Sun

Measurements of external mass-transfer coefficients for dissolution have been made with benzoic acid tablets with a diameter of 13 mm and approximately 3 mm thick, using two different dissolution systems. One system has been a beaker with a platform for the tablet and either 80 mL or 120 mL of water, with three different types of stirrers, and the other has been a USP dissolution apparatus 2 (paddle) with either 200 mL or 900 mL water. Various stirring speeds have also been used in the different pieces of equipment. The same mass-transfer coefficient may potentially be obtained from the same tablet by adjusting the operating conditions in the two different devices. The ranges of the external mass-transfer coefficients measured in both devices overlapped significantly, with the range being 0.193–4.48 × 10−5 m s−1 in the beaker and stirrer system and 0.222–3.45 × 10−5 m s−1 in the USP dissolution apparatus 2. Dimensional analysis of the results, using Sherwood and Reynolds numbers, shows that the Ranz–Marshall correlation provides a lower bound for estimates of the Sherwood numbers measured experimentally. Calculations of time constants for mass transfer suggest that mass transfer may be a rate-limiting step for dissolution and food digestion under some circumstances. The range of mass-transfer coefficients measured here is representative of other measurements from the literature, and the use of the Ranz–Marshall correlation supports the suggestion that this range of values should be generally expected in most situations.


2021 ◽  
pp. 240-302
Author(s):  
Thorvald Abel Engh ◽  
Geoffrey K. Sigworth ◽  
Anne Kvithyld

Impurities are transferred out at the boundary of the liquid. Velocities normal to the boundary are small. Therefore, for efficient removal contact areas and times should be large. Transfer depends on the chemical and physical properties of the liquid and the phase that captures the impurities at the boundary. This phase may be a liquid, gas (vacuum) or solid. Properties can be described in terms of equilibrium and empirical mass transfer coefficients. Vacuum may be applied to remove volatile elements. Refining can be carried out by partial solidification or fractional crystallisation, using the segregation that occurs during freezing of an alloy. Finally, an element can be added to form a reactive compound followed by removal of the compound by sedimentation or filtration.


2021 ◽  
Vol 71 (2) ◽  
pp. 109-120
Author(s):  
Gužela Štefan ◽  
Dzianik František

Abstract A number of industrial operations are linked to mass transfer. The mass transfer coefficient value is necessary to know when designing the industrial equipment in which mass transfer occurs. There are various mass transfer coefficients, as well as equations for their calculation. However, the value of these coefficients determined according to these equations often has to be corrected for the given conditions. The aim of the article is to state the conversion relations - the correction factors enabling the calculation of the mass transfer coefficients values corresponding to the given conditions.


2021 ◽  
Vol 8 ◽  
pp. 100180
Author(s):  
S. Matthes ◽  
T. Merbach ◽  
J. Fitschen ◽  
M. Hoffmann ◽  
M. Schlüter

Processes ◽  
2021 ◽  
Vol 9 (9) ◽  
pp. 1517
Author(s):  
Hung-Ta Wu ◽  
Chin-Chun Chung

The depression in vapor pressure caused by adding desiccant to liquid water can be regarded as the driving force for the dehumidification process. The vapor pressure depends on the temperature and the concentration. Therefore, the purpose in this study is to discuss the mass transfer performance affected by operating variables and to show that the vapor pressure is a key factor affecting the mass transfer performance for absorbing water vapor by triethylene glycol (TEG) solution. The experimental results showed that the mass transfer coefficients were decreased with increases in the temperature and increased with increases in the concentration, respectively, while the mass transfer coefficients were increased with increases in the vapor pressure depression. Although both the average error is within 5% among the mass transfer correlation involving the vapor pressure and that involving the temperature and the concentration in predicting the mass transfer coefficient, there are just two terms, those are vapor pressure and fluid flow rate, associated with operating variables used in the mass transfer correlation. The depression in vapor pressure was not only proved to be the driving force for absorbing water vapor by a desiccant solution, but also a key factor affecting the mass transfer performance.


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