Influence of intermolecular hydrogen bonding interactions on the electrocatalytic reduction of CO2 to CO by 6,6'‐amine substituted rhenium bipyridine complexes

2021 ◽  
Author(s):  
Ashley N. Hellman ◽  
Ralf Haiges ◽  
Smaranda C Marinescu
Keyword(s):  
Hydrogen Bonding ◽  
Intermolecular Hydrogen Bonding ◽  
Electrocatalytic Reduction ◽  
Hydrogen Bonding Interactions ◽  
Reduction Of Co2 ◽  
Electrocatalytic Reduction Of Co2

Interrogating heterobimetallic co-catalytic responses for the electrocatalytic reduction of CO2 using supramolecular assembly

2016 ◽  
Vol 45 (40) ◽  
pp. 15942-15950 ◽  
Author(s):  
Charles W. Machan ◽  
Clifford P. Kubiak
Keyword(s):  
Hydrogen Bonding ◽  
Supramolecular Assembly ◽  
Supramolecular System ◽  
Electrocatalytic Reduction ◽  
Hydrogen Bonding Interactions ◽  
Reduction Of Co2 ◽  
Electrocatalytic Reduction Of Co2

The use of hydrogen-bonding interactions to direct the non-covalent assembly of a heterobimetallic supramolecular system with Re and Mn bipyridine-based electrocatalysts is reported.

Nanoporous bismuth for the electrocatalytic reduction of CO2 to formate

2021 ◽  
Author(s):  
Xiaoyan Wang ◽  
Zhiyong Wang ◽  
Xianbo Jin
Keyword(s):  
Electrocatalytic Reduction ◽  
Electrocatalytic Performance ◽  
Primary Particles ◽  
Reduction Of Co2 ◽  
Electrocatalytic Reduction Of Co2

The size of the primary particles of nanoporous Bi has a great impact on the electrocatalytic performance of Bi for the reduction of CO2 to formate.

scholarly journals Efficient electrocatalytic reduction of CO2 to CO on an electrodeposited Zn porous network

2018 ◽  
Vol 97 ◽  
pp. 87-90 ◽  
Author(s):  
Yu Lu ◽  
Bin Han ◽  
Chongchong Tian ◽  
Jian Wu ◽  
Dongsheng Geng ◽  
...  
Keyword(s):  
Electrocatalytic Reduction ◽  
Porous Network ◽  
Reduction Of Co2 ◽  
Electrocatalytic Reduction Of Co2

Electrocatalytic reduction of CO2 to ethylene and ethanol through hydrogen-assisted C–C coupling over fluorine-modified copper

2020 ◽  
Vol 3 (6) ◽  
pp. 478-487 ◽  
Author(s):  
Wenchao Ma ◽  
Shunji Xie ◽  
Tongtong Liu ◽  
Qiyuan Fan ◽  
Jinyu Ye ◽  
...  
Keyword(s):  
Electrocatalytic Reduction ◽  
Reduction Of Co2 ◽  
Electrocatalytic Reduction Of Co2

Enhanced Electrocatalytic Reduction of CO2 via Chemical Coupling between Indium Oxide and Reduced Graphene Oxide

Nano Letters ◽  
2019 ◽  
Vol 19 (6) ◽  
pp. 4029-4034 ◽  
Author(s):  
Zhirong Zhang ◽  
Fawad Ahmad ◽  
Wanghui Zhao ◽  
Wensheng Yan ◽  
Wenhua Zhang ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Reduced Graphene Oxide ◽  
Indium Oxide ◽  
Electrocatalytic Reduction ◽  
Reduced Graphene ◽  
Chemical Coupling ◽  
Reduction Of Co2 ◽  
Electrocatalytic Reduction Of Co2

Synthese, Struktur und thermisches Verhalten von Thiophosphorsäuretriamid SP(NH2)3 [1] / Synthesis, Structure, and Thermal Behaviour of Phosphorothionic Triamide SP(ΝΗ2)3 [1]

1989 ◽  
Vol 44 (8) ◽  
pp. 942-945 ◽  
Author(s):  
Wolfgang Schnick
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonding ◽  
Thermal Properties ◽  
Single Crystal ◽  
Melting Temperature ◽  
Intermolecular Hydrogen Bonding ◽  
X Ray ◽  
Hydrogen Bonding Interactions ◽  
Ray Methods ◽  
Single Bonds

Phosphorothionic triamide SP(NH2)3 is obtained by slow addition of SPCl3 dissolved in dry CH2Cl2 to a satured solution of NH3 in CH2Cl2 at —50°C. Ammonium chloride is removed from the resulting precipitate by treatment with HNEt2 followed by extraction with CH2Cl2. Coarse crystalline SP(NH2)3 is obtained after recrystallization from dry methanol. The crystal structure of SP(NH2)3 has been determined by single crystal X-ray methods (Pbca; a = 922.3(1), b = 953.8(1), c = 1058.4(2) pm, Z = 8). In the crystals the molecules show non-crystallographic point symmetry C8. The P—S bond (195.4(1) pm) is slightly longer than in SPCl3. From P—N bond lengths of about 166 pm a significant electrostatic strengthening of the P—N single bonds is assumed. Weak intermolecular hydrogen bonding interactions (N —H · · · N ≥ 329.5 pm; N — H · · · S ≥ 348.3 pm) are observed.Investigation of thermal properties shows a melting temperature of 115°C for SP(NH2)3. According to combined DTA/TG and MS investigations above this temperature the compound decomposes by evolution of H2S and NH3 to yield amorphous phosphorus(V)nitride.

Tailoring the Selectivity of Bimetallic Copper–Palladium Nanoalloys for Electrocatalytic Reduction of CO2 to CO

2018 ◽  
Vol 1 (2) ◽  
pp. 883-890 ◽  
Author(s):  
Dong Chen ◽  
Qiaofeng Yao ◽  
Penglei Cui ◽  
Hui Liu ◽  
Jianping Xie ◽  
...  
Keyword(s):  
Electrocatalytic Reduction ◽  
Reduction Of Co2 ◽  
Electrocatalytic Reduction Of Co2
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