Bonding in Diborane-Metal Complexes: A Quantum-Chemical and Experimental Study of Complexes Featuring Early and Late Transition Metals

2013 ◽  
Vol 19 (23) ◽  
pp. 7395-7409 ◽  
Author(s):  
Arne Wagner ◽  
Elisabeth Kaifer ◽  
Hans-Jörg Himmel
Keyword(s):  
Experimental Study ◽  
Transition Metals ◽  
Metal Complexes ◽  
Quantum Chemical ◽  
Late Transition Metals ◽  
Late Transition

Axial Chirality in Square-Planar Metal Complexes

1998 ◽  
Vol 53 (9) ◽  
pp. 1035-1038 ◽  
Author(s):  
Dieter Enders ◽  
Heike Gielen ◽  
Klaus Breuer
Keyword(s):  
Transition Metals ◽  
Metal Complexes ◽  
Axial Chirality ◽  
Late Transition Metals ◽  
Nucleophilic Carbenes ◽  
Square Planar ◽  
Late Transition ◽  
Planar Ligands

Metal complexes with a square-planar arrangement of ligands are frequently found for the late Transition Metals. The incorporation of C1-symmetrical planar ligands (e.g. nucleophilic carbenes) in an orientation perpendicular to the square-plane of the complex leads to various isomers which are characterized by means of an axis of chirality employing the well established Cahn-Ingold-Prelog -R/S-nomenclature.

Site isolated complexes of late transition metals grafted on silica: challenges and chances for synthesis and catalysis

2014 ◽  
Vol 4 (9) ◽  
pp. 2724-2740 ◽  
Author(s):  
Martino Rimoldi ◽  
Antonio Mezzetti
Keyword(s):  
Transition Metal ◽  
Transition Metals ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Late Transition Metal ◽  
Oxide Supports ◽  
Late Transition Metals ◽  
Reducing Conditions ◽  
Quo Vadis ◽  
Late Transition

Grafting, quo vadis? The reasons for the aggregation of late transition metal complexes on oxide supports under reducing conditions and/or in the presence of π-accepting ligands are discussed, and strategies are suggested to prevent it.

Organic synthesis with the most abundant transition metal–iron: from rust to multitasking catalysts

2021 ◽  
Author(s):  
Sujoy Rana ◽  
Jyoti Prasad Biswas ◽  
Sabarni Paul ◽  
Aniruddha Paik ◽  
Debabrata Maiti
Keyword(s):  
Transition Metal ◽  
Transition Metals ◽  
Organic Synthesis ◽  
Present Review ◽  
Synthetic Chemistry ◽  
Late Transition Metals ◽  
Iron Chemistry ◽  
Late Transition

The promising aspects of iron in synthetic chemistry are being explored for three-four decades as a green and eco-friendly alternative to late transition metals. This present review unveils these rich iron-chemistry towards different transformations.

Fe2CS2 MXene: a promising electrode for Al-ion batteries

Nanoscale ◽  
2020 ◽  
Vol 12 (9) ◽  
pp. 5324-5331 ◽  
Author(s):  
Sangjin Lee ◽  
Sung Chul Jung ◽  
Young-Kyu Han
Keyword(s):  
Transition Metals ◽  
Ion Transport ◽  
Fold Increase ◽  
Late Transition Metals ◽  
Late Transition

Using late transition metals and sulfur termination groups for MXene leads to 104-fold increase in Al-ion transport and 2.2-fold increase in Al-ion capacity, respectively.

PNP-Pincer-Type Phosphaalkene Complexes of Late Transition Metals

2016 ◽  
Vol 16 (5) ◽  
pp. 2314-2323 ◽  
Author(s):  
Fumiyuki Ozawa ◽  
Yumiko Nakajima
Keyword(s):  
Transition Metals ◽  
Late Transition Metals ◽  
Late Transition

scholarly journals Multiple Bonding Involving Late Transition Metals. The Case of a Silver−Oxo Complex.

2000 ◽  
Vol 39 (6) ◽  
pp. 1336-1336
Author(s):  
Thomas R. Cundari ◽  
Jeremy N. Harvey ◽  
Thomas R. Klinckman ◽  
Wentao Fu
Keyword(s):  
Transition Metals ◽  
Late Transition Metals ◽  
Multiple Bonding ◽  
Late Transition
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