A kind of P-25 TiO2 films coated nickel foam was synthesized by a facile dip-coating/calcination route, and used to fabricate a continuous-flow three-phase photocatalytic reactor. The morphology, crystal phase structure, surface composition and specific surface area of P-25 films coated nickel foam were investigated by field emission scanning electron microscope (FE-SEM), X-ray diffractometer (XRD), X-ray photoelectron spectroscopy (XPS) and nitrogen adsorption-desorption measurements, respectively. The results indicated that the coated/ calcined P-25 films had the porous surface structure fabricated by nano-sized titanium dioxide consisted of two crystal phases and incorporated with a NiO interlayer. The increase of P-25 contents enhanced the specific surface area; however, 20 percent of initial P-25 sol would result in visible large cracks because of too high P-25 content and consequently cause the peeling of films. The photocatalytic activities of nickel foam with different coating amounts of P-25 for the degradation of quinoline aqueous solutions were investigated with a continuous-flow three-phase photocatalytic reactor based on the P-25 films coated nickel foam. The results suggested that nickel foam coated with 10 percent of P-25 sol had an optimal photocatalytic activity for the degradation of quinoline aqueous solutions. The continuous-flow three-phase photocatalytic reactor fabricated with P-25 films coated nickel foam with an optimal P-25 coating amount shows high photocatalytic activity and stability for the degradation of quinoline aqueous solutions and industrial wastewater. The treated industrial wastewater meets the international discharge standard.
From the Lindlar Catalyst to Supported Ligand-Modified Palladium Nanoparticles: Selectivity Patterns and Accessibility Constraints in the Continuous-Flow Three-Phase Hydrogenation of Acetylenic Compounds
