Kinetics of degradation of sulfur mustard and sarin simulants on HKUST-1 metal organic framework

2012 ◽  
Vol 41 (40) ◽  
pp. 12346 ◽  
Author(s):  
Anuradha Roy ◽  
Avanish K. Srivastava ◽  
Beer Singh ◽  
Dilip Shah ◽  
Timir Haran Mahato ◽  
...  
Keyword(s):  
Sulfur Mustard ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Kinetics Of Degradation ◽  
Kinetics Of ◽  
Organic Framework

Postsynthetic Incorporation of a Singlet Oxygen Photosensitizer in a Metal-Organic Framework for Fast and Selective Oxidative Detoxification of Sulfur Mustard

2016 ◽  
Vol 23 (1) ◽  
pp. 214-218 ◽  
Author(s):  
Ashlee J. Howarth ◽  
Cassandra T. Buru ◽  
Yangyang Liu ◽  
Ann M. Ploskonka ◽  
Karel J. Hartlieb ◽  
...  
Keyword(s):  
Singlet Oxygen ◽  
Sulfur Mustard ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Oxidative Detoxification ◽  
Organic Framework

Preparation, optimization and evolution of the kinetic mechanism of an Fe-MIL-88A metal–organic framework

CrystEngComm ◽  
2019 ◽  
Vol 21 (3) ◽  
pp. 544-553 ◽  
Author(s):  
Elham Bagherzadeh ◽  
Seyed Mojtaba Zebarjad ◽  
Hamid Reza Madaah Hosseini ◽  
Pierre Chagnon
Keyword(s):  
Morphological Changes ◽  
Metal Organic Framework ◽  
Kinetic Mechanism ◽  
Nucleation Mechanism ◽  
Growth Behavior ◽  
Kinetics Of Crystallization ◽  
Metal Organic ◽  
Statistical Studies ◽  
Kinetics Of ◽  
Organic Framework

Investigating the kinetics of crystallization, growth behavior and morphological changes through statistical studies of Fe-MIL-88A suggested an autocatalytic nucleation mechanism.

scholarly journals Kinetics of cooperative CO2 adsorption in diamine-appended variants of the metal–organic framework Mg2(dobpdc)

2020 ◽  
Vol 11 (25) ◽  
pp. 6457-6471 ◽  
Author(s):  
Jeffrey D. Martell ◽  
Phillip J. Milner ◽  
Rebecca L. Siegelman ◽  
Jeffrey R. Long
Keyword(s):  
Adsorption Kinetics ◽  
Carbon Capture ◽  
Co2 Adsorption ◽  
Metal Organic Framework ◽  
Performance Properties ◽  
Metal Organic ◽  
Kinetics Of ◽  
Insight Into ◽  
Organic Framework

An in-depth investigation of the CO2 adsorption kinetics of a promising class of cooperative carbon capture materials offers new insight into their structure-performance properties.

scholarly journals An exceptionally stable octacobalt-cluster-based metal–organic framework for enhanced water oxidation catalysis

2019 ◽  
Vol 10 (42) ◽  
pp. 9859-9864 ◽  
Author(s):  
Ning-Yu Huang ◽  
Jian-Qiang Shen ◽  
Zi-Ming Ye ◽  
Wei-Xiong Zhang ◽  
Pei-Qin Liao ◽  
...  
Keyword(s):  
Reaction Kinetics ◽  
Adsorption Energy ◽  
Water Oxidation ◽  
Metal Organic Framework ◽  
Oxidation Catalysis ◽  
Cobalt Ions ◽  
Water Oxidation Catalysis ◽  
Metal Organic ◽  
Kinetics Of ◽  
Organic Framework

The site, capping four coplanar cobalt ions, has a near-optimal OH− adsorption energy, which is beneficial to accelerate the reaction kinetics of water oxidation catalysis.

scholarly journals Air oxidation of sulfur mustard gas simulants using a pyrene-based metal–organic framework photocatalyst

2019 ◽  
Vol 10 ◽  
pp. 2422-2427 ◽  
Author(s):  
Ghada Ayoub ◽  
Mihails Arhangelskis ◽  
Xuan Zhang ◽  
Florencia Son ◽  
Timur Islamoglu ◽  
...  
Keyword(s):  
Sulfur Mustard ◽  
Metal Organic Framework ◽  
Oxidative Degradation ◽  
Chemical Warfare Agents ◽  
Mustard Gas ◽  
Air Oxidation ◽  
Substitution Pattern ◽  
Warfare Agents ◽  
Metal Organic ◽  
Organic Framework

We demonstrate a microporous metal–organic framework NU-400 based on a 2,7-disubstituted pyrene linker as a highly efficient photosensitizer for generating singlet oxygen and subsequent oxidative degradation of chemical warfare agents (CWAs). The high activity of NU-400 permits photocatalytic conversion of the 2-chloroethyl ethyl sulfide (CEES) mustard gas simulant into a benign sulfoxide derivative, in air, with less than 15 minutes’ half-life. This is a considerable improvement to NU-1000, based on a 1,3,6,8-tetrasubstituted pyrene unit, demonstrating how variation of the substitution pattern of a metal–organic framework linker permits modification of its photoactive behavior.

Metal–organic framework derived yolk–shell NiS2/carbon spheres for lithium–sulfur batteries with enhanced polysulfide redox kinetics

2019 ◽  
Vol 55 (22) ◽  
pp. 3243-3246 ◽  
Author(s):  
Yaxi Tian ◽  
Huawen Huang ◽  
Guoxue Liu ◽  
Ran Bi ◽  
Lei Zhang
Keyword(s):  
Shell Structure ◽  
Metal Organic Framework ◽  
Electrochemical Performances ◽  
Carbon Spheres ◽  
Redox Kinetics ◽  
Lithium Sulfur Batteries ◽  
Metal Organic ◽  
Kinetics Of ◽  
Lithium Sulfur ◽  
Organic Framework

A yolk–shell NiS2/C–S cathode exhibits enhanced electrochemical performances in lithium–sulfur batteries due to the improved redox kinetics of polysulfide confined within the yolk–shell structure.

scholarly journals Protective Fabrics: Metal-Organic Framework Textiles for Rapid Photocatalytic Sulfur Mustard Simulant Detoxification

Matter ◽  
2020 ◽  
Vol 2 (2) ◽  
pp. 404-415 ◽  
Author(s):  
Dennis T. Lee ◽  
Jovenal D. Jamir ◽  
Gregory W. Peterson ◽  
Gregory N. Parsons
Keyword(s):  
Sulfur Mustard ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Protective Fabrics ◽  
Organic Framework

Degradation of sulfur mustard and 2-chloroethyl ethyl sulfide on Cu–BTC metal organic framework

2012 ◽  
Vol 162 ◽  
pp. 207-212 ◽  
Author(s):  
Anuradha Roy ◽  
Avanish Kumar Srivastava ◽  
Beer Singh ◽  
T.H. Mahato ◽  
Dilip Shah ◽  
...  
Keyword(s):  
Sulfur Mustard ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework
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