N,S‐Co‐Doped Porous Carbon Nanofiber Films Derived from Fullerenes (C 60 ) as Efficient Electrocatalysts for Oxygen Reduction and a Zn–Air Battery

Author(s):  
Zhimin He ◽  
Peng Wei ◽  
Ning Chen ◽  
Jiantao Han ◽  
Xing Lu
2019 ◽  
Vol 7 (46) ◽  
pp. 26272-26278 ◽  
Author(s):  
Yan Kong ◽  
Yan Li ◽  
Bin Yang ◽  
Zhongjian Li ◽  
Yao Yao ◽  
...  

A metal-free B, N co-doped porous carbon nanofiber with a synergistic effect was developed for efficient electrocatalytic nitrogen reduction reaction in basic solution.


RSC Advances ◽  
2020 ◽  
Vol 10 (39) ◽  
pp. 23091-23096
Author(s):  
Hao Cheng ◽  
Zhengyuan Zhou ◽  
Tao Liu

Nitrogen, phosphorus co-doped porous carbon nanofiber is as electrode modified material to fabricate an electro-chemiluminescent sensor for detecting cyproheptadine.


2017 ◽  
Vol 239 ◽  
pp. 1-9 ◽  
Author(s):  
Lina Xu ◽  
Hao Fan ◽  
Lixin Huang ◽  
Jianling Xia ◽  
Shouhai Li ◽  
...  

Author(s):  
Tao Wang ◽  
Oluwafunmilola Ola ◽  
Qijian Niu ◽  
Yuhao Lu ◽  
Malcom Frimpong Dapaah ◽  
...  

Recently, electrocatalysts for oxygen reduction reactions (ORRs) as well as oxygen evolution reactions (OERs) hinged on electrospun nanofiber composites have attracted wide research attention. Transition metal elements and heteroatomic doping are important methods used to enhance their catalytic performances. Lately, the construction of electrocatalysts based on metal-organic framework (MOF) electrospun nanofibers has become a research hotspot. In this work, bimetallic NixCoy-ZIF nanocrystals were synthesized in an aqueous solution, followed by NixCoy-ZIF/PAN electrospun nanofiber precursors, which were prepared by a simple electrospinning method. Bimetal (Ni-Co) porous carbon nanofiber catalysts doped with nitrogen, oxygen, and sulfur elements were obtained at high-temperature carbonization treatment in different atmospheres (Ar, Air, and H2S), respectively. The morphological properties, structures, and composition were characterized by SEM, TEM, SAED, XRD, and XPS. Also, the specific surface area of materials and their pore size distribution was characterized by BET. Linear sweep voltammetry curves investigated catalyst performances towards oxygen reduction and evolution reactions. Importantly, Ni1Co2-ZIFs/PAN-Ar yielded the best ORR activity, whereas Ni1Co1-ZIFs/PAN-Air exhibited the best OER performance. This work provides significant guidance for the preparation and characterization of multi-doped porous carbon nanofibers carbonized in different atmospheres.


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