scholarly journals Preparation and Characterization of Multi-doped Porous Carbon Nanofibers from Carbonization in Different Atmospheres and Their Oxygen Electrocatalytic Properties Research

Author(s):  
Tao Wang ◽  
Oluwafunmilola Ola ◽  
Qijian Niu ◽  
Yuhao Lu ◽  
Malcom Frimpong Dapaah ◽  
...  

Recently, electrocatalysts for oxygen reduction reactions (ORRs) as well as oxygen evolution reactions (OERs) hinged on electrospun nanofiber composites have attracted wide research attention. Transition metal elements and heteroatomic doping are important methods used to enhance their catalytic performances. Lately, the construction of electrocatalysts based on metal-organic framework (MOF) electrospun nanofibers has become a research hotspot. In this work, bimetallic NixCoy-ZIF nanocrystals were synthesized in an aqueous solution, followed by NixCoy-ZIF/PAN electrospun nanofiber precursors, which were prepared by a simple electrospinning method. Bimetal (Ni-Co) porous carbon nanofiber catalysts doped with nitrogen, oxygen, and sulfur elements were obtained at high-temperature carbonization treatment in different atmospheres (Ar, Air, and H2S), respectively. The morphological properties, structures, and composition were characterized by SEM, TEM, SAED, XRD, and XPS. Also, the specific surface area of materials and their pore size distribution was characterized by BET. Linear sweep voltammetry curves investigated catalyst performances towards oxygen reduction and evolution reactions. Importantly, Ni1Co2-ZIFs/PAN-Ar yielded the best ORR activity, whereas Ni1Co1-ZIFs/PAN-Air exhibited the best OER performance. This work provides significant guidance for the preparation and characterization of multi-doped porous carbon nanofibers carbonized in different atmospheres.

2019 ◽  
Vol 7 (46) ◽  
pp. 26272-26278 ◽  
Author(s):  
Yan Kong ◽  
Yan Li ◽  
Bin Yang ◽  
Zhongjian Li ◽  
Yao Yao ◽  
...  

A metal-free B, N co-doped porous carbon nanofiber with a synergistic effect was developed for efficient electrocatalytic nitrogen reduction reaction in basic solution.


RSC Advances ◽  
2015 ◽  
Vol 5 (127) ◽  
pp. 104822-104828 ◽  
Author(s):  
Juan Zhang ◽  
Zhian Zhang ◽  
Xingxing Zhao

A graphene/N-doped porous carbon nanofiber (RGO/NPC) composite was designed as an anode material for sodium-ion batteries (SIBs). A microstructure of fine and uniform N-doped porous carbon nanofibers decorated on 2D RGO sheets was obtained.


RSC Advances ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 4053-4061
Author(s):  
Xiaohong Chen ◽  
Zhiyong Xue ◽  
Kai Niu ◽  
Xundao Liu ◽  
Wei lv ◽  
...  

We developed a facile, yet general, approach for preparing Li–fluorine codoped porous carbon nanofiber (Li–F–PCNF) composites, which showed excellent hydrogen storage performance.


RSC Advances ◽  
2017 ◽  
Vol 7 (87) ◽  
pp. 55224-55231 ◽  
Author(s):  
Hexuan Zhang ◽  
Zhengzheng Xie ◽  
Yanbo Wang ◽  
Xiaohong Shang ◽  
Pengfei Nie ◽  
...  

With β-CD as both pore-forming reagent and carbon precursor, conductive porous carbon nanofibers are fabricated with excellent capacitive deionization performance.


2015 ◽  
Vol 3 (47) ◽  
pp. 24082-24094 ◽  
Author(s):  
Hao Niu ◽  
Xue Yang ◽  
He Jiang ◽  
Dan Zhou ◽  
Xin Li ◽  
...  

Hierarchical ZnCo2O4 nanoneedle arrays are vertically grown on porous carbon nanofibers (PCFs) to form a core–shell heterostructure through a facile hydrothermal method followed by thermal treatment.


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