scholarly journals Hydrogenation of secondary amides using phosphane oxide and frustrated Lewis pair catalysis

2021 ◽  
Author(s):  
Laura Köring ◽  
Nikolai A. Sitte ◽  
Markus Bursch ◽  
Stefan Grimme ◽  
Jan Henry Hakan Paradies
Keyword(s):  
Frustrated Lewis Pair ◽  
Secondary Amides

Towards the development of FLP-catalyzed hydrogenations of tertiary and secondary carboxylic amides

Synthesis ◽  
2021 ◽  
Author(s):  
Jan Paradies ◽  
Laura Köring ◽  
Nikolai A. Sitte
Keyword(s):  
Development Process ◽  
Organic Molecules ◽  
Frustrated Lewis Pair ◽  
Secondary Amides ◽  
Insight Into

The development of the frustrated Lewis pair catalyzed hydrogenation of tertiary and secondary amides is reviewed. Detailed insight into our strategies in order to overcome challenges during the reaction development process is provided. Furthermore, the developed chemistry is extended to the hydrogenation of poly amides and trifluoroacetyl amides for the convenient introduction of trifluoro ethyl groups into organic molecules.

Bis(perchlorocatecholato)silane and Heteroleptic Bidonors: Hidden Frustrated Lewis Pairs by Ring Strain

2021 ◽  
Author(s):  
Deborah Hartmann ◽  
Sven Braner ◽  
Lutz Greb
Keyword(s):  
Ammonia Borane ◽  
Frustrated Lewis Pairs ◽  
Ring Strain ◽  
Frustrated Lewis Pair ◽  
Lewis Pairs

Bis(perchlorocatecholato)silane and bidentate N,N- or N,P-heteroleptic donors form hexacoordinated complexes. Depending on the ring strain and hemilability in the adducts, Frustrated Lewis pair reactivity with aldehydes and catalytic ammonia borane...

scholarly journals A frustrated-Lewis-pair approach to catalytic reduction of alkynes to cis-alkenes

2013 ◽  
Vol 5 (8) ◽  
pp. 718-723 ◽  
Author(s):  
Konstantin Chernichenko ◽  
Ádám Madarász ◽  
Imre Pápai ◽  
Martin Nieger ◽  
Markku Leskelä ◽  
...  
Keyword(s):  
Catalytic Reduction ◽  
Frustrated Lewis Pair

Borocation catalysis

2017 ◽  
Vol 46 (15) ◽  
pp. 4874-4887 ◽  
Author(s):  
P. Eisenberger ◽  
C. M. Crudden
Keyword(s):  
Pair Type ◽  
Frustrated Lewis Pair ◽  
Catalytic Reactivity

The synthesis, stability and catalytic reactivity of borocations are described in the context of their reaction in frustrated Lewis pair-type processes.

scholarly journals H2 activation by hydrogenase-inspired NiFe catalyst using frustrated Lewis pair: effect of buffer and halide ion in the heterolytic H–H bond cleavage

RSC Advances ◽  
2021 ◽  
Vol 11 (45) ◽  
pp. 28420-28432
Author(s):  
Miho Isegawa ◽  
Takahiro Matsumoto ◽  
Seiji Ogo
Keyword(s):  
Fossil Fuels ◽  
Bond Cleavage ◽  
Clean Fuel ◽  
Frustrated Lewis Pair

Hydrogen is a clean fuel alternative to fossil fuels, and it is vital to develop catalysts for its efficient activation and production.

Nickel-Catalyzed Suzuki-Miyaura Cross-Coupling of C-F Bonds

2021 ◽  
Author(s):  
Tianhao Zhang ◽  
Itsuki Nohira ◽  
Naoto Chatani
Keyword(s):  
Cross Coupling ◽  
Secondary Amides

The efficient Suzuki-Miyaura cross-coupling of ortho-fluoro aromatic secondary amides with aryl boronates is described. The use of KOtBu is essential for the reaction to proceed. The function of the base...

Sign in / Sign up

Export Citation Format

Share Document