scholarly journals Bright Luminescence by Combining Chiral [2.2]Paracyclophane with a Boron‐Nitrogen‐Doped Polyaromatic Hydrocarbon Building Block

Author(s):  
Mario R. Rapp ◽  
Wolfgang Leis ◽  
Francesco Zinna ◽  
Lorenzo Di Bari ◽  
Tamara Arnold ◽  
...  
2019 ◽  
Author(s):  
Matthew Morgan ◽  
Maryam Nazari ◽  
Thomas Pickl ◽  
J. Mikko Rautiainen ◽  
Heikki M. Tuononen ◽  
...  

The electrophilic borylation of 2,5-diarylpyrazines results in the formation of boron-nitrogen doped dihydroindeno[1,2-<i>b</i>]fluorene which can be synthesized via mildly air-sensitive techniques and the end products handled readily under atmosphereic conditions. Through transmetallation via diarylzinc reagents a series of derivatives were sythesized which show broad absorption profiles that highlight the versatility of this backbone to be used in organic solar cell devices. These compounds can be synthesized in large yields, in alow number of steps and functionalized at many stages along the way providing a large depth of possibilities. Exploratory device paramaters were studied and show PCE of 2%.


2016 ◽  
Vol 120 (31) ◽  
pp. 6287-6302 ◽  
Author(s):  
Sirous Yourdkhani ◽  
Michał Chojecki ◽  
Michał Hapka ◽  
Tatiana Korona

2020 ◽  
Vol 26 (29) ◽  
pp. 6608-6621 ◽  
Author(s):  
Jacopo Dosso ◽  
Tommaso Battisti ◽  
Benjamin D. Ward ◽  
Nicola Demitri ◽  
Colan E. Hughes ◽  
...  

NANO ◽  
2019 ◽  
Vol 14 (07) ◽  
pp. 1950080
Author(s):  
Hao Hu ◽  
Xiaogang Sun ◽  
Wei Chen ◽  
Jie Wang ◽  
Xu Li ◽  
...  

Carbon nanotubes (CNTs) were doped by ammonium borate as the sources of nitrogen and boron. Under the protection of Ar gas, boron-nitrogen doped CNTs were prepared through nitriding and boronization at high temperature. It is a conductive additive. Then, the obtained CNTs were mixed with activated carbon (AC), SP, sodium dodecyl sulfate (SDS), and cellulose fiber to prepare electrodes. With all the materials, a symmetric electric double-layer supercapacitor (EDLC) was assembled. Next, the materials and electrodes were also characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The factors, chemical connections, and specific surface area of the CNTs were analyzed by X-ray energy spectrum analysis (EDS), X-ray photoelectron spectroscopy (XPS), as well as a specific surface area and porosimetry analyzer (BET). In addition, the electrochemical performances of electric double-layer capacitors were tested with the help of cyclic voltammetry, constant-current charging and discharging, and so on. From the results, we can make a conclusion, that is, both B and N atoms were added into the CNTs and formed bonds successfully with carbon atoms mutually. Besides, the specific surface area is about 1.5 times than that of the CNT. When the charge/discharge current density reaches 50[Formula: see text]mA/g, we can find that the mass specific capacitance of the capacitor can run up to 32.19[Formula: see text]F/g. Also, we observe that the maximum power density is close to 220[Formula: see text]W/kg (700[Formula: see text]mA/g), and the energy density can arrive 9.31[Formula: see text]Wh/kg (50[Formula: see text]mA/g). Based on the impedance test, the electrodes are characterized with low impedance. After 2000 cycles, the boron-nitrogen doped double-layer capacitors maintain a capacitance retention ratio of above 95%. Its power density can still achieve 220[Formula: see text]W/kg when the energy density keeps at 3.46[Formula: see text]Wh/kg. In other words, the electrochemical performance functions of the electric double-layer capacitors are enhanced while the CNTs serve as the electrodes.


Synlett ◽  
2019 ◽  
Vol 31 (03) ◽  
pp. 211-222
Author(s):  
Junzhi Liu ◽  
Xinliang Feng

Bottom-up organic synthesis serves as an efficient method to provide atomically precise heteroatom-doped polycyclic aromatic hydrocarbons (PAHs) with not only well-defined size and edge structures but also specific concentrations and positions of the heteroatoms. We provide a plenary account of the preparation of nitrogen-doped PAHs (N-PAHs) through 1,3-dipolar cycloaddition between different dipolarophiles, as well as pyrazine-type N-doped diaza-hexa-peri-hexabenzocoronene (diaza-HBC). Additionally, we present the synthesis of a class of helical N-charged PAHs, including one charged aza[5]helicene and two charged aza[4]helicenes. Moreover, the bottom-up organic synthesis strategy is further extended to the construction of novel nitrogen-boron-nitrogen (NBN)-containing PAHs. Finally, we discuss the synthesis of four-coordinate boron chromophores containing 6,12,18-tris(alkyl amine)-5,11,17-triazatrinaphthylene derivative ligands.1 Introduction2 Nitrogen-Doped PAHs Based on Dibenzo-9a-azaphenalene (DBAP)3 Cationic Nitrogen-Doped Helical PAHs4 Nitrogen–Boron–Nitrogen-Doped PAHs5 Conclusion and Outlook


Synthesis ◽  
2019 ◽  
Vol 51 (22) ◽  
pp. 4147-4152 ◽  
Author(s):  
Michael Fingerle ◽  
Simon Stocker ◽  
Holger F. Bettinger

A dibenzoperylene motif featuring a doubly boron–nitrogen-doped bay region is accessible from an aniline derivative in six steps in good overall yield. Two n-butyl groups provide the BN-doped polycyclic aromatic hydrocarbon with sufficient solubility in common organic solvents. The synthesis sequence allows installation of a second boron atom next to a weakly nucleophilic nitrogen by using a protected boron species. The title compound shows blue fluorescence, an extremely high fluorescence quantum yield, and an interesting doped bay region.


2007 ◽  
Vol 23 (10) ◽  
pp. 1647-1651
Author(s):  
LIANG Yun-Xiao ◽  
◽  
◽  
SHUI Miao ◽  
LI Rong-Sheng

2018 ◽  
Vol 20 (17) ◽  
pp. 11673-11681 ◽  
Author(s):  
Sunghu Kim ◽  
Byung-Kuk Yoo ◽  
Yuri Choi ◽  
Byeong-Su Kim ◽  
Oh-Hoon Kwon

The non-exponential decay of the photoluminescence of carbon dots are analyzed using stretched exponential fit functions to reflect the heterogeneity in their luminescent surface states.


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