ChemInform Abstract: EFFECT OF A NEIGHBORING TRIMETHYLSILYL GROUP ON THE PHOTOCHEMICAL AND MASS SPECTRAL FRAGMENTATION PATHWAYS OF S-ALKYL THIOACETATES

1974 ◽  
Vol 5 (42) ◽  
pp. no-no
Author(s):  
T. I. ITO ◽  
W. P. WEBER
1992 ◽  
Vol 70 (4) ◽  
pp. 1028-1032 ◽  
Author(s):  
Nigel J. Bunce ◽  
H. Stewart McKinnon ◽  
Randy J. Schnurr ◽  
Sam R. Keum ◽  
Erwin Buncel

The mass spectral fragmentation pathways of a series of phenylazoxypyridine-N-oxides have been studied under electron impact conditions using tandem mass spectrometry. Besides simple C—N cleavages, the azoxypyridine-N-oxides undergo deep-seated rearrangements directly from the molecular ion. In addition, the spectra are complicated by a purely chemical reduction of the N—O functionalities that occurs in the ion source prior to ionization.


1990 ◽  
Vol 25 (1) ◽  
pp. 14-20 ◽  
Author(s):  
Jehuda Yinon ◽  
William C. Brumley ◽  
George M. Brilis ◽  
Suryanarayana Bulusu

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