ChemInform Abstract: HALOGEN-HYDROGEN HALIDE CATALYSIS OF THE OXIDATION OF THIOLS TO DISULFIDES BY SULFOXIDES

1975 ◽  
Vol 6 (42) ◽  
pp. no-no
Author(s):  
O. G. LOWE
Keyword(s):  
Hydrogen Halide

Hydrogen-halide versus alkyl-halide oxidative addition in dimethyl platinum(II) complexes: Crystal structure of [PtBr2(bpy)]

2007 ◽  
Vol 360 (8) ◽  
pp. 2661-2668 ◽  
Author(s):  
Badri Z. Momeni ◽  
Saeideh Hamzeh ◽  
Simin S. Hosseini ◽  
Frank Rominger
Keyword(s):  
Crystal Structure ◽  
Alkyl Halide ◽  
Oxidative Addition ◽  
Hydrogen Halide

Preparation and Z-E isomerization of substituted nitrostyrenes

1986 ◽  
Vol 51 (5) ◽  
pp. 1094-1099 ◽  
Author(s):  
Ivo Bláha ◽  
Ladislav Lešetický
Keyword(s):  
Equilibrium Constants ◽  
Hydrogen Halide ◽  
Double Bonds

This study concerns the synthesis of β-sustituted β-nitrostyrenes by two procedures: addition of nitryl halogenides to double bonds, connected with the elimination of hydrogen halide, and condensation of aldehydes with substituted nitromethanes, and it compares the utilizability of the two procedures. Two of the substances prepared, methyl (Z)-nitro-3-phenylpropenoate and (Z)-4-phenyl-β-nitro-β-buten-2-one, were submitted to Z-E isomerization at various temperatures, and thermodynamic isomerization parameters were estimated from the dependence of the equilibrium constants on temperature.

Kerr Constants of the Hydrogen Halide Gases

Nature ◽  
1936 ◽  
Vol 138 (3484) ◽  
pp. 248-248
Author(s):  
C. H. DOUGLAS CLARK ◽  
E. C. HUMPHRIES
Keyword(s):  
Hydrogen Halide ◽  
Kerr Constants

Etude des dérivés sulfohydroxylés des halogénures de bore et des cycles dérivés du borsulfol I. Synthèses et mécanismes réactionnels

1973 ◽  
Vol 51 (2) ◽  
pp. 292-301 ◽  
Author(s):  
Jean Bouix ◽  
Roger Hillel
Keyword(s):  
Hydrogen Halide ◽  
Boron Halides

By the action of H2S on boron halides (other than fluoride) one obtains the new substitution products BX2SH, BX(SH)2, and B(SH)3 along with the corresponding hydrogen halide. These halogenosulfhydroboranes are unstable and cyclize to cyclic boron sulfides, either (BSSH)3 or (BSX)3.In the case of boron bromide it is possible, by controlling the ratio of the reactants and the temperature of the reaction, to promote the formation of one of the three possible substitution products. Then by encouraging cyclization one may obtain, rapidly and selectively, either (BSSH)3 or (BSBr)3.Synthesis of (BSCl)3 was accomplished by dissolution of (BSSH)3 in liquid BCl3 and that of (BSI)3 by the action of H2S on solid BI3. [Journal translation]

Molecular beam study of the hydrogen/hydrogen halide system: New results on the exchange reaction

1980 ◽  
Vol 72 (4) ◽  
pp. 2896-2897 ◽  
Author(s):  
W. H. Beck ◽  
R. Götting ◽  
J. P. Toennies ◽  
K. Winkelmann
Keyword(s):  
Exchange Reaction ◽  
Molecular Beam ◽  
Hydrogen Halide ◽  
Halide System

THE CHEMISTRY OF ETHYLENE OXIDE: V. THE REACTION OF ETHYLENE OXIDE WITH HALIDE IONS IN NEUTRAL AND ACID SOLUTION

1952 ◽  
Vol 30 (3) ◽  
pp. 169-176 ◽  
Author(s):  
A. M. Eastham ◽  
G. A. Latremouille
Keyword(s):  
Aqueous Solution ◽  
Ethylene Oxide ◽  
Acid Solution ◽  
Activation Energies ◽  
Hydrogen Halide ◽  
Halide Ions ◽  
Neutral Aqueous Solution ◽  
Rate Of Hydrolysis ◽  
Acid Catalyzed ◽  
Hydrolysis Of

The rates of reaction of halide ions with ethylene oxide in neutral aqueous solution and the rate of hydrolysis of ethylene oxide in acid solution have been measured and the activation energies determined. From these data and from the ratio of glycol to chlorohydrin formed when ethylene oxide reacts with excess aqueous hydrogen halide, the rates of the acid-catalyzed addition of halide ions to ethylene oxide at 25 °C. have been estimated.

Infra-red cryogenic studies. Part 1.—Hydrogen halide multimers

1969 ◽  
Vol 65 (0) ◽  
pp. 3150-3158 ◽  
Author(s):  
A. J. Barnes ◽  
H. E. Hallam ◽  
G. F. Scrimshaw
Keyword(s):  
Hydrogen Halide ◽  
Infra Red
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