ChemInform Abstract: PHOTOCATALYTIC REACTIONS. 1. PHOTOLYSIS OF WATER AND PHOTOREDUCTION OF NITROGEN ON TITANIUM DIOXIDE

1978 ◽  
Vol 9 (6) ◽  
Author(s):  
G. N. SCHRAUZER ◽  
T. D. GUTH
2001 ◽  
Vol 36 (7) ◽  
pp. 1419-1425 ◽  
Author(s):  
Shuji Matsuo ◽  
Yasuhiro Anraku ◽  
Sunao Yamada ◽  
Tsuneo Honjo ◽  
Taku Matsuo ◽  
...  

Author(s):  
N. Shestakov ◽  
D. Alekseeva ◽  
D. Polosina

The article discusses the possibility of reducing the atmospheric environmental load of highways by applying compositions with photocatalytic properties to acoustic screens. It is found that the amount of nitrogen oxides on the territory of the city of Moscow exceeds the MPC norms. Therefore, a potential way to reduce the level of the average daily and maximum one-time MPC of nitrogen oxides is proposed, when using coatings of traditional acoustic screens with photocatalytic compositions. Titanium dioxide in anatase form is considered as a photocatalytic agent. To reduce the density and increase the porosity of cement compositions, a cellulosic suspension obtained by saturation in an aqueous medium with subsequent homogenization is introduced. The effect of cellulose in the considered cement systems in combination with a photocatalytic agent has been investigated. By the method of mathematical planning, a two-factor compositional experiment is compiled. In result, the degrees of influence of titanium dioxide and cellulose additives on the strength, density and water absorption of the composites under study are established. The study of the structure of the obtained composites shows that TiO2 is mainly located on the surface of cellulose fibers, which theoretically increases the useful surface for photocatalytic reactions and, as a consequence, the final efficiency of the compositions.


2003 ◽  
Vol 5 (3) ◽  
pp. 159-166 ◽  
Author(s):  
Evgeny I. Kapinus ◽  
Tatyana A. Khalyavka ◽  
Valentina V. Shimanovskaya ◽  
Tatyana I. Viktorova ◽  
Vladimir V. Strelko

Dispersed optically pure anatase, rutile and two-phase samples of titanium dioxide were prepared using a sol-gel technique. In particle of two-phase samples, the anatase nuclei are surrounded by a rutile envelope. Content of anatase in the two-phase particles varied between 20 and 80%. Particles of all theTiO2samples had a globular shape of diameter between 10 and 30μm. When compared to the corresponding technical-grade samples, the optically pure anatase and rutile demonstrated higher photocatalytic activity in the destruction of tetradecylpyridinium chloride, Methylene Blue and tetrachlorofluorescein as well as in reduction ofCr2O7,MnO4,[Fe(CN)6]3−and[Fe(CN)6]4−. The photocatalytic reactions bring about the reduction of the inorganic anions to yield water insoluble substances and mineralization of the organic compounds. Rate constant of the all above processes do not depend on specific surface area ofTiO2and adsorption of the substrates on theTiO2samples. The rutile calcined at 1027K exhibits the highest specific rate constants. Exposure toγ-radiation increases photocatalytic activity of the dispersedTiO2. The influence ofTiO2and substrate on the photocatalytic reactions is caused by the influence of these factors on the formation of reactive electron hole pair and on the efficiency of the interfacial electron transfer.


2001 ◽  
Vol 34 (6) ◽  
pp. 844-847 ◽  
Author(s):  
TOSHINORI TSURU ◽  
TERUTAKA TOYOSADA ◽  
TOMOHISA YOSHIOKA ◽  
MASASHI ASAEDA

2013 ◽  
Vol 795 ◽  
pp. 483-487
Author(s):  
N.M.N. Azira ◽  
M. Asri Idris ◽  
Dewi Suriyani Che Halin ◽  
M.N.B. Derman ◽  
Mohd Arif Anuar Mohd Salleh

The titanium dioxide (TiO2) is a semiconductor oxide photocatalys, which is chemically and biologically inert but exhibits excellent photolytic activity in the ultraviolet (UV) region. Progress in photocatalytic water disinfection requires understanding both concepts of TiO2 semiconductor as well the biochemistry of microorganisms. The advantage and disadvantage for current water purifications are discussed. Finally, the photocatalytic reactions to water disinfection and detoxification using solar energy.


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