ChemInform Abstract: EFFECT OF TEMPERATURE OF REDUCTION ON THE ACTIVITY AND SELECTIVITY OF A COPRECIPITATED NICKEL-ALUMINA CATALYST FOR THE FISCHER-TROPSCH AND METHANATION REACTIONS

1978 ◽  
Vol 9 (7) ◽  
Author(s):  
E. B. M. DOESBURG ◽  
S. ORR ◽  
J. R. H. ROSS ◽  
L. L. VAN REIJEN
2015 ◽  
Vol 5 (8) ◽  
pp. 4193-4201 ◽  
Author(s):  
Julien Scalbert ◽  
Isabelle Clémençon ◽  
Philippe Lecour ◽  
Laure Braconnier ◽  
Fabrice Diehl ◽  
...  

Simultaneous investigation of structure and surface of a Co/Al2O3 catalyst during Fischer–Tropsch synthesis: identification of beneficial and disadvantageous phenomena.


Catalysts ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 846
Author(s):  
Omid Akbarzadeh ◽  
Solhe F. Alshahateet ◽  
Noor Asmawati Mohd Zabidi ◽  
Seyedehmaryam Moosavi ◽  
Amir Kordijazi ◽  
...  

The effect of reaction temperature, syngas space velocity, and catalyst stability on Fischer-Tropsch reaction was investigated using a fixed-bed microreactor. Cobalt and Manganese bimetallic catalysts on carbon nanotubes (CNT) support (Co-Mn/CNT) were synthesized via the strong electrostatic adsorption (SEA) method. For testing the performance of the catalyst, Co-Mn/CNT catalysts with four different manganese percentages (0, 5, 10, 15, and 20%) were synthesized. Synthesized catalysts were then analyzed by TEM, FESEM, atomic absorption spectrometry (AAS), and zeta potential sizer. In this study, the temperature was varied from 200 to 280 °C and syngas space velocity was varied from 0.5 to 4.5 L/g.h. Results showed an increasing reaction temperature from 200 °C to 280 °C with reaction pressure of 20 atm, the Space velocity of 2.5 L/h.g and H2/CO ratio of 2, lead to the rise of CO % conversion from 59.5% to 88.2% and an increase for C5+ selectivity from 83.2% to 85.8%. When compared to the other catalyst formulation, the catalyst sample with 95% cobalt and 5% manganese on CNT support (95Co5Mn/CNT) performed more stable for 48 h on stream.


RSC Advances ◽  
2017 ◽  
Vol 7 (13) ◽  
pp. 7793-7800 ◽  
Author(s):  
Venkat Ramana Rao Pendyala ◽  
Wilson D. Shafer ◽  
Gary Jacobs ◽  
Michela Martinelli ◽  
Dennis E. Sparks ◽  
...  

The effects of co-fed ammonia in synthesis gas on the activity and product selectivities of a typical cobalt catalyst (0.5% Pt–25% Co/Al2O3) were investigated during the Fischer–Tropsch synthesis using a continuously stirred tank reactor (CSTR).


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