ChemInform Abstract: THE FORMATION OF ALKYL ACETATE IN THE REACTION OF TRIALKYLBORANE WITH LEAD(IV) ACETATE OR PHENYLIODOSO ACETATE

1978 ◽  
Vol 9 (24) ◽  
Author(s):  
Y. MASUDA ◽  
A. ARASE
Keyword(s):  
1992 ◽  
Vol 48 (1) ◽  
pp. 279-290
Author(s):  
A. Abdel Razik ◽  
M. S. Metwally ◽  
M. F. El-Hadi ◽  
M. A. El Wardany

Author(s):  
Gail Sansone-Bazzano ◽  
Gaetano Bazzano ◽  
Ronald M. Reisner ◽  
James G. Hamilton

1971 ◽  
Vol 20 (12) ◽  
pp. 868-870
Author(s):  
Yoshiki OKAMOTO ◽  
Hiroshi SAKURAI
Keyword(s):  

2021 ◽  
Vol 3 (9) ◽  
Author(s):  
Daiki Nagata ◽  
Nagatoshi Nishiwaki

AbstractAcetic acid derivatives such as ethyl acetate have been considered to be negative to the iodoform test because of the predominant hydrolysis leading to acetic acid. We clarified the immiscible property of the ester was the actual reason for the negative result. When THF or 1-propanol was used as a solvent, even alkyl acetate underwent the iodoform reaction; however, it cannot be used as qualitative test because of high solubility of iodoform into these solvents. This problem was overcome by conducting the test in methanol. Indeed, not only alkyl acetates but also N,N-dimethylacetamide showed positive to the iodoform test producing a yellow precipitates.


Sign in / Sign up

Export Citation Format

Share Document