ChemInform Abstract: HOMOLOGOUS CHROMIUM, MOLYBDENUM, AND TUNGSTEN DERIVATIVES OF 6-CHLORO-2-HYDROXYPYRIDINE. INDUCTIVE EFFECTS ON THE METAL-METAL BOND LENGTH

1980 ◽  
Vol 11 (36) ◽  
Author(s):  
F. A. COTTON ◽  
W. H. ILSLEY ◽  
W. KAIM
Keyword(s):  
Bond Length ◽  
Metal Bond ◽  
Metal Metal ◽  
Inductive Effects ◽  
Derivatives Of ◽  
And Tungsten

Determination of Nanoparticle Size by Measuring the Metal–Metal Bond Length: The Case of Palladium Hydride

2014 ◽  
Vol 119 (1) ◽  
pp. 854-861 ◽  
Author(s):  
Jianqiang Wang ◽  
Qi Wang ◽  
Xinghua Jiang ◽  
Zhongneng Liu ◽  
Weimin Yang ◽  
...  
Keyword(s):  
Bond Length ◽  
Nanoparticle Size ◽  
Palladium Hydride ◽  
Metal Bond ◽  
Metal Metal

Stereochemie der Metall-Metall-Bindung: Darstellung und Struktur von Co2(CO)4C5H5P(CH3)2 / Stereochemistry of the Metal-Metal Bond: Preparation and Structure of Co2(CO)4C5H5P(CH3)2

1978 ◽  
Vol 33 (5) ◽  
pp. 537-541 ◽  
Author(s):  
Egbert Keller ◽  
Heinrich Vahrenkamp
Keyword(s):  
Crystal Structure ◽  
Bond Length ◽  
Structure Analysis ◽  
Crystal Structure Analysis ◽  
Title Complex ◽  
Systematic Variation ◽  
Metal Bond ◽  
Metal Metal

Abstract The title complex 4 was prepared from η-C3H5Co(CO)3 and η-C5H5(CO)Co-P(CH3)2H. It completes the series of PR2-and AsR2-bridged homodinuclear complexes C2(CO)7C5H5-As(CH3)2, Mn2(CO)6C5H5As(CH3)2, and Fe2(CO)5C5H5P(CH3)2. Its crystal structure analysis reveals the systematic variation of the ligand distribution along the series which depends only on the number of ligands present and not on given coordination geometries. The metal-metal bond length in 4 is mainly determined by the stereochemical require-ments of the bridging phosphido ligand.

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