Role of ferryl (FeO2+) complexes in oxygen atom transfer reactions. Mechanism of iron(II) porphyrin catalyzed oxygenation of triphenylphosphine

1980 ◽  
Vol 102 (18) ◽  
pp. 5945-5947 ◽  
Author(s):  
Der-Hang Chin ◽  
Gerd N. La Mar ◽  
Alan L. Balch
Keyword(s):  
Oxygen Atom ◽  
Transfer Reactions ◽  
Atom Transfer ◽  
Oxygen Atom Transfer ◽  
Oxygen Atom Transfer Reactions ◽  
Atom Transfer Reactions ◽  
Reactions Mechanism

Nonclassical oxygen atom transfer reactions of an eight-coordinate dioxomolybdenum(vi) complex

2021 ◽  
Author(s):  
Leila G. Ranis ◽  
Jacqueline Gianino ◽  
Justin M. Hoffman ◽  
Seth N. Brown
Keyword(s):  
Oxygen Atom ◽  
Transfer Reaction ◽  
Transfer Reactions ◽  
Atom Transfer ◽  
Oxygen Atom Transfer ◽  
Oxygen Atom Transfer Reactions ◽  
Atom Transfer Reactions ◽  
Oxygen Atoms

Eight-coordinate MoO2(DOPOQ)2 can donate two oxygen atoms to substrates such as phosphines in a four-electron nonclassical oxygen atom transfer reaction.

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