ChemInform Abstract: X-RAY PHOTOELECTRON SPECTRA OF INORGANIC MOLECULES. 31. SATELLITE STRUCTURE ASSOCIATED WITH THE CORE-ELECTRON BINDING ENERGIES OF ALKYL AND ARYL ISOCYANIDE COMPLEXES OF THE TRANSITION METALS

1982 ◽  
Vol 13 (40) ◽  
Author(s):  
W. S. MIALKI ◽  
R. A. WALTON
1977 ◽  
Vol 49 (2) ◽  
pp. 213-217 ◽  
Author(s):  
M.Salim Banna ◽  
David C. Frost ◽  
Charles A. McDowell ◽  
Louis Noodleman ◽  
Barry Wallbank

1992 ◽  
Vol 7 (8) ◽  
pp. 1984-1986 ◽  
Author(s):  
Shigemi Kohiki ◽  
Mikihiko Nishitani ◽  
Takayuki Negami ◽  
Takahiro Wada

The Cu, In, and Se core-level electron binding energies of the p-type Cu–In–Se–N thin film were larger than those of the n-type Cu–In–Se thin film. The positive shift of the core-electron binding energies for the Cu–In–Se–N film is consistent with that expected from the conduction types of the films. Holes were positioned in the Cu–Se antibonding orbitals of the Cu–In–Se–N film. The analysis using the Auger parameter revealed that the Cu–Se bonding interaction is stronger for the Cu–In–Se–N film than for the Cu–In–Se film.


1988 ◽  
Vol 53 (3) ◽  
pp. 425-432 ◽  
Author(s):  
Zdeněk Bastl ◽  
Heidrun Gehlmann

The core electron binding energies of eighteen compounds containing iodine in different oxidation states ranging from (-I) to (VII) have been measured. The observed chemical shifts differ from the literature data. The anticipated existence of hexavalent iodine in certain compounds has not been demonstrated. The relative subshell photoemission intensities of iodine have been determined. Empirically derived atomic sensitivity factors and theoretical photoionization cross-sections have been used to calculate the surface stoichiometry. The concentration ratios obtained via the two methods are compared. In agreement with generally accepted view the results of this comparison imply that, for quantitative surface analysis, empirical values should be used rather than theoretical data.


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