ChemInform Abstract: Stacking Structure with Trimolecular Units of Donor-Acceptor-Donor in a Charge-Transfer Complex of Dinaphtho(1,2-b:1′,2′-e)-1,4-dithiin with Tetracyanoquinodimethane

ChemInform ◽  
1988 ◽  
Vol 19 (30) ◽  
Author(s):  
K. KOBAYASHI ◽  
M. TAKAHASHI ◽  
H. KOBAYASHI
Keyword(s):  
Charge Transfer ◽  
Charge Transfer Complex ◽  
Donor Acceptor ◽  
A Charge ◽  
Stacking Structure

Complexation par transfert de charge de la chlorpromazine en présence d'iode; action thyroïdienne sécondaire de cette molécule

1984 ◽  
Vol 62 (9) ◽  
pp. 1807-1811 ◽  
Author(s):  
Anne-Catherine Absil ◽  
Jacques Buxeraud ◽  
Claude Raby
Keyword(s):  
Charge Transfer ◽  
Thermodynamic Parameters ◽  
Molecular Interaction ◽  
Electron Spectroscopy ◽  
Formation Constant ◽  
Charge Transfer Complex ◽  
Tertiary Amines ◽  
Acceptor Interaction ◽  
Donor Acceptor ◽  
A Charge

Molecular interaction between iodine and chlorpromazine is investigated by electron spectroscopy. Iodine forms a charge transfer complex with chlorpromazine, with 1:1 stoichiometry and of the n–σ type. The values of the formation constant (Kc at20 °C = 3166 ± 19 L mol−1) and thermodynamic parameters (ΔH0 = −11.22 ± 0.11 kcal mol−1, ΔS0 = −22.29 ± 0.38 cal mol−1 K−1) show a strong donor–acceptor interaction, comparable to that obtained with tertiary amines. The formation constant is compared to those obtained with antithyroid molecules. Chlorpromazine appears to have no effect on the intrathyroid cycle of iodine.

scholarly journals Multi-configurational Ehrenfest simulations of ultrafast nonadiabatic dynamics in a charge-transfer complex

2018 ◽  
Vol 149 (24) ◽  
pp. 244107 ◽  
Author(s):  
Tianji Ma ◽  
Matteo Bonfanti ◽  
Pierre Eisenbrandt ◽  
Rocco Martinazzo ◽  
Irene Burghardt
Keyword(s):  
Charge Transfer ◽  
Charge Transfer Complex ◽  
Nonadiabatic Dynamics ◽  
A Charge

The Reagent Diphenyldiselane/Iodine: No Phenylselenenyl Iodide but a Charge Transfer Complex with Cyclic Moieties

1988 ◽  
Vol 27 (3) ◽  
pp. 431-433 ◽  
Author(s):  
Silvia Kubiniok ◽  
Wolf-Walther du Mont ◽  
Siegfried Pohl ◽  
Wolfgang Saak
Keyword(s):  
Charge Transfer ◽  
Charge Transfer Complex ◽  
A Charge

Possible low-temperature phase transition of Langmuir–Blodgett films of a charge–transfer complex detected by ESR

1998 ◽  
Vol 327-329 ◽  
pp. 391-394
Author(s):  
Keiichi Ikegami ◽  
Shin-ichi Kuroda ◽  
Tomoyuki Akutagawa ◽  
Taro Konuma ◽  
Takayoshi Nakamura ◽  
...  
Keyword(s):  
Phase Transition ◽  
Charge Transfer ◽  
Low Temperature ◽  
Charge Transfer Complex ◽  
Temperature Phase ◽  
Langmuir Blodgett ◽  
Langmuir Blodgett Films ◽  
Temperature Phase Transition ◽  
A Charge ◽  
Low Temperature Phase
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