ChemInform Abstract: The Chemistry of N-Substituted Benzotriazoles. Part 11. The Preparation of Tertiary Amines Containing Tertiaryl-Alkyl Groups from Ketones, Secondary Amines, and Organometallic Reagents.

ChemInform ◽  
1989 ◽  
Vol 20 (23) ◽  
Author(s):  
A. R. KATRITZKY ◽  
Z. NAJZAREK ◽  
Z. DEGA-SZAFRAN
Keyword(s):  
Secondary Amines ◽  
Tertiary Amines ◽  
Organometallic Reagents ◽  
Alkyl Groups

Reaction of arylmethylenemalonaldehydes with some nucleophiles

1987 ◽  
Vol 52 (11) ◽  
pp. 2699-2709 ◽  
Author(s):  
Dalimil Dvořák ◽  
Zdeněk Arnold
Keyword(s):  
Inorganic Anions ◽  
Secondary Amines ◽  
Tertiary Amines ◽  
Primary And Secondary Amines ◽  
Dipolar Structure

Reaction of arylmethylenemalonaldehydes with tributylphosphine and tertiary amines affords compounds of dipolar structure whereas reaction with primary and secondary amines leads to 1,4-addition products. Salts of nucleophilic inorganic anions add to arylmethylenemalonaldehydes under formation of salts of substituted malonaldehydes.

Convenient Preparations of Imines and Symmetrical Secondary Amines Possessing Primary or Secondary Alkyl Groups

Synthesis ◽  
1991 ◽  
Vol 1991 (09) ◽  
pp. 703-708 ◽  
Author(s):  
Alan R. Katritzky ◽  
Xiaohong Zhao ◽  
Gregory J. Hitchings
Keyword(s):  
Secondary Amines ◽  
Alkyl Groups
Sign in / Sign up

Export Citation Format

Share Document