ChemInform Abstract: Radiotracers in Fluorine Chemistry. Part 12. Reactions Between Cesium Fluoride and Arsenic Pentafluoride, Boron Trifluoride, Sulfur Tetrafluoride, Carbonyl Fluoride, and Carbon Dioxide Under Heterogeneous Conditions at Room Temperatur

ChemInform ◽  
1989 ◽  
Vol 20 (36) ◽  
Author(s):  
K. W. DIXON ◽  
J. M. WINFIELD
Keyword(s):  
Carbon Dioxide ◽  
Boron Trifluoride ◽  
Fluorine Chemistry ◽  
Cesium Fluoride ◽  
Sulfur Tetrafluoride ◽  
Carbonyl Fluoride

CBF3O2 Carbon dioxide - boron trifluoride (1/1)

2005 ◽  
pp. 1-1
Author(s):  
G. Graner ◽  
E. Hirota ◽  
T. Iijima ◽  
K. Kuchitsu ◽  
D. A. Ramsay ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Boron Trifluoride

Observation of Carbonyl Fluoride, Ketene, Acetic Acid and Fluorocarbene Produced by an Electric Discharge within a Nozzle by Molecular Beam Fourier Transform Microwave Spectroscopy. A Reaction via a Cycloaddition for Carbonyl Fluoride and Keten?

2000 ◽  
Vol 55 (8) ◽  
pp. 695-705 ◽  
Author(s):  
D. H. Sutter ◽  
H. Dreizler
Keyword(s):  
Carbon Dioxide ◽  
Acetic Acid ◽  
Fourier Transform ◽  
Molecular Beam ◽  
Reaction Path ◽  
Microwave Spectroscopy ◽  
Electrical Discharges ◽  
Microwave Spectrometer ◽  
Precursor Molecules ◽  
Carbonyl Fluoride

Abstract A molecular beam Fourier transform microwave spectrometer, designed for the study of chemical reactions within electrical discharges, is described in detail. Applications include the production of carbonyl fluoride, ketene, acetic acid, and difluorocarbene. For the production of carbonyl fluoride and ketene with 1,1-difluoroethylene and carbon dioxide as precursor molecules a reaction path via a 2+2 cycloaddition is proposed.

The fluoroformate ion, FCO2−. An ion cyclotron resonance study of the gas phase Lewis acidity of carbon dioxide and related isoelectronic species

1978 ◽  
Vol 56 (8) ◽  
pp. 1069-1074 ◽  
Author(s):  
Terrance Brian McMahon ◽  
Colleen Joan Northcott
Keyword(s):  
Carbon Dioxide ◽  
Gas Phase ◽  
Lewis Acidity ◽  
Ion Cyclotron Resonance ◽  
Dissociation Energies ◽  
Ion Molecule Reactions ◽  
Gas Phase Acidity ◽  
Gas Phase Ion ◽  
Carbonyl Fluoride

The gas phase ion molecule reactions of a number of potential fluoride donors with carbon dioxide and carbonyl fluoride have been studied. By determination of preferential directions of fluoride transfer the fluoride affinities of carbon dioxide and carbonyl fluoride have been bracketed and found to be 33 ± 3 kcal/mol and 35 + 3 kcal/mol respectively. In addition, from gas phase acidity studies of acetyl fluoride and 2-fluoropropene the fluoride affinities of ketene and allene have been calculated to be 38 ± 2 kcal/mol and 15 ± 2 kcal/mol respectively. The order of fluoride affinities (Lewis acidities) of carbon dioxide, ketene, and allene have been examined and explained in terms of the electron affinities of the F—C(A)(B) species (A,B=O,CH2) and the C—F bond dissociation energies. These quantities have been estimated and the latter interpreted on the basis of the π bond energies of the three compounds.

ChemInform Abstract: Carboxylation of Alkynylsilanes with Carbon Dioxide Mediated by Cesium Fluoride in DMSO.

ChemInform ◽  
2013 ◽  
Vol 44 (40) ◽  
pp. no-no
Author(s):  
Misato Yonemoto-Kobayashi ◽  
Kiyofumi Inamoto ◽  
Yoshiyuki Tanaka ◽  
Yoshinori Kondo
Keyword(s):  
Carbon Dioxide ◽  
Cesium Fluoride

Boron trifluoride catalyzed polymerisation of 2-substituted-2-oxazolines in supercritical carbon dioxide

2007 ◽  
Vol 9 (9) ◽  
pp. 948 ◽  
Author(s):  
Carlota Veiga de Macedo ◽  
Mara Soares da Silva ◽  
Teresa Casimiro ◽  
Eurico J. Cabrita ◽  
Ana Aguiar-Ricardo
Keyword(s):  
Carbon Dioxide ◽  
Supercritical Carbon Dioxide ◽  
Boron Trifluoride ◽  
Supercritical Carbon
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