ChemInform Abstract: Metal Complexes with Tetrapyrrole Ligands. Part 59. Redox Potentials, Near-IR Absorption, Ionic Radii, and Ring-Ring Distance in Metal(III) Bis(tetraphenylporphyrinate) Systems with Porphyrin Rings in Different Oxidation States.

ChemInform ◽  
2010 ◽  
Vol 22 (50) ◽  
pp. no-no
Author(s):  
J. W. BUCHLER ◽  
P. HAMMERSCHMITT ◽  
I. KAUFELD ◽  
J. LOEFFLER
Keyword(s):  
Metal Complexes ◽  
Oxidation States ◽  
Ir Absorption ◽  
Redox Potentials ◽  
Ionic Radii ◽  
Near Ir ◽  
Porphyrin Rings

scholarly journals The Near IR Absorption of Metal Complexes with Flavin Free Radicals.

1964 ◽  
Vol 18 ◽  
pp. 1320-1321 ◽  
Author(s):  
Anders Ehrenberg ◽  
Peter Hemmerich ◽  
Martin Nilsson ◽  
Attilio Melera ◽  
Lennart Nilsson
Keyword(s):  
Free Radicals ◽  
Metal Complexes ◽  
Ir Absorption ◽  
Near Ir

Plasmon-assisted interaction of Si with light, for cancer hyperthermia and electromagnetic energy harvest

2020 ◽  
Vol 92 (2) ◽  
pp. 20101
Author(s):  
Behnam Kheyraddini Mousavi ◽  
Morteza Rezaei Talarposhti ◽  
Farshid Karbassian ◽  
Arash Kheyraddini Mousavi
Keyword(s):  
Silicon Nanowires ◽  
Metallic Nanoparticles ◽  
Near Infrared ◽  
Optical Transition ◽  
Electromagnetic Energy ◽  
Energy Harvest ◽  
Absorption Enhancement ◽  
Ir Absorption ◽  
Absorption Mechanism ◽  
Near Ir

Metal-assisted chemical etching (MACE) is applied for fabrication of silicon nanowires (SiNWs). We have shown the effect of amorphous sheath of SiNWs by treating the nanowires with SF6 and the resulting reduction of absorption bandwidth, i.e. making SiNWs semi-transparent in near-infrared (IR). For the first time, by treating the fabricated SiNWs with copper containing HF∕H2O2∕H2O solution, we have generated crystalline nanowires with broader light absorption spectrum, up to λ = 1 μm. Both the absorption and photo-luminescence (PL) of the SiNWs are observed from visible to IR wavelengths. It is found that the SiNWs have PL at visible and near Infrared wavelengths, which may infer presence of mechanisms such as forbidden gap transitions other can involvement of plasmonic resonances. Non-radiative recombination of excitons is one of the reasons behind absorption of SiNWs. Also, on the dielectric metal interface, the absorption mechanism can be due to plasmonic dissipation or plasmon-assisted generation of excitons in the indirect band-gap material. Comparison between nanowires with and without metallic nanoparticles has revealed the effect of nanoparticles on absorption enhancement. The broader near IR absorption, paves the way for applications like hyperthermia of cancer while the optical transition in near IR also facilitates harvesting electromagnetic energy at a broad spectrum from visible to IR.

Near-IR Absorption Spectra for the Buckminsterfullerene Anions: An Experimental and Theoretical Study

1992 ◽  
Author(s):  
Del R. Lawson ◽  
Daniel L. Feldheim ◽  
Colby A. Foss ◽  
Peter K. Dorhoug ◽  
C. M. Elliott
Keyword(s):  
Absorption Spectra ◽  
Theoretical Study ◽  
Ir Absorption ◽  
Near Ir ◽  
Ir Absorption Spectra

Near-IR absorption of water vapor: Pressure dependence of line strengths and an upper limit for continuum absorption

2005 ◽  
Vol 232 (2) ◽  
pp. 223-230 ◽  
Author(s):  
M. Aldener ◽  
S.S. Brown ◽  
H. Stark ◽  
J.S. Daniel ◽  
A.R. Ravishankara
Keyword(s):  
Water Vapor ◽  
Vapor Pressure ◽  
Pressure Dependence ◽  
Water Vapor Pressure ◽  
Ir Absorption ◽  
Continuum Absorption ◽  
Near Ir ◽  
Upper Limit ◽  
Line Strengths

Picosecond transient-IR absorption of unsaturated transition metal complexes

1990 ◽  
Author(s):  
Kenneth G. Spears ◽  
Liang Wang ◽  
Xinming Zhu ◽  
Steven M. Arrivo
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Ir Absorption

On-chip methane sensing by near-IR absorption signatures in a photonic crystal slot waveguide

2011 ◽  
Vol 36 (6) ◽  
pp. 984 ◽  
Author(s):  
Wei-Cheng Lai ◽  
Swapnajit Chakravarty ◽  
Xiaolong Wang ◽  
Cheyun Lin ◽  
Ray T. Chen
Keyword(s):  
Photonic Crystal ◽  
Slot Waveguide ◽  
Ir Absorption ◽  
Near Ir ◽  
On Chip
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