ChemInform Abstract: Reaction of Sodium Aluminum Hydride with Selected Organic Compounds Containing Representative Functional Groups. Comparison of the Reducing Characteristics of Lithium and Sodium Aluminum Hydrides.

ChemInform ◽  
2010 ◽  
Vol 24 (51) ◽  
pp. no-no
Author(s):  
J. S. CHA ◽  
H. C. BROWN
Keyword(s):  
Functional Groups ◽  
Organic Compounds ◽  
Aluminum Hydride ◽  
Sodium Aluminum Hydride ◽  
Aluminum Hydrides

scholarly journals Non-Enzymatic Desymmetrization Reactions in Aqueous Media

Symmetry ◽  
2021 ◽  
Vol 13 (4) ◽  
pp. 720
Author(s):  
Satomi Niwayama
Keyword(s):  
Natural Products ◽  
Total Synthesis ◽  
Functional Groups ◽  
Organic Compounds ◽  
Recent Progress ◽  
Aqueous Media ◽  
Building Blocks ◽  
Organic Reactions ◽  
Environmentally Benign ◽  
Enzymatic Desymmetrization

Symmetric organic compounds are generally obtained inexpensively, and therefore they can be attractive building blocks for the total synthesis of various pharmaceuticals and natural products. The drawback is that discriminating the identical functional groups in the symmetric compounds is difficult. Water is the most environmentally benign and inexpensive solvent. However, successful organic reactions in water are rather limited due to the hydrophobicity of organic compounds in general. Therefore, desymmetrization reactions in aqueous media are expected to offer versatile strategies for the synthesis of a variety of significant organic compounds. This review focuses on the recent progress of desymmetrization reactions of symmetric organic compounds in aqueous media without utilizing enzymes.

Dehydriding properties of Ti or/and Zr-doped sodium aluminum hydride prepared by ball-milling

2007 ◽  
Vol T129 ◽  
pp. 95-98 ◽  
Author(s):  
Xue-Zhang Xiao ◽  
Li-Xin Chen ◽  
Xin-Hua Wang ◽  
Shou-Quan Li ◽  
Zhou-Ming Hang ◽  
...  
Keyword(s):  
Ball Milling ◽  
Aluminum Hydride ◽  
Sodium Aluminum Hydride
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