ChemInform Abstract: Room Temperature and Phosphine Free Palladium Catalyzed Direct C-2 Arylation of Indoles.

ChemInform ◽  
2008 ◽  
Vol 39 (29) ◽  
Author(s):  
Nathalie Lebrasseur ◽  
Igor Larrosa
Keyword(s):  
Room Temperature ◽  
Palladium Catalyzed

Water-Soluble Imine Ligand/Palladium-Catalyzed Suzuki Reaction at Room Temperature

2010 ◽  
Vol 31 (10) ◽  
pp. 1277-1280
Author(s):  
Chun LIU ◽  
Qijian NI ◽  
Pingping HU ◽  
Hao YUAN ◽  
Zilin JIN
Keyword(s):  
Room Temperature ◽  
Suzuki Reaction ◽  
Water Soluble ◽  
Palladium Catalyzed

Palladium-Catalyzed Mono-α-arylation of Acetone at Room Temperature

2015 ◽  
Vol 21 (31) ◽  
pp. 11006-11009 ◽  
Author(s):  
Preston M. MacQueen ◽  
Alicia J. Chisholm ◽  
Breanna K. V. Hargreaves ◽  
Mark Stradiotto
Keyword(s):  
Room Temperature ◽  
Palladium Catalyzed

Palladium-catalyzed Mizoroki–Heck-type reactions of [Ph2SRfn][OTf] with alkenes at room temperature

2016 ◽  
Vol 52 (80) ◽  
pp. 11893-11896 ◽  
Author(s):  
Shi-Meng Wang ◽  
Hai-Xia Song ◽  
Xiao-Yan Wang ◽  
Nan Liu ◽  
Hua-Li Qin ◽  
...  
Keyword(s):  
Room Temperature ◽  
Cross Coupling ◽  
Palladium Catalyzed

The first Pd-catalyzed Mizoroki–Heck-type cross-coupling of phenylsulfonium salts with alkenes was disclosed at room temperature.

scholarly journals Room-Temperature Palladium-Catalyzed CH Activation:ortho-Carbonylation of Aniline Derivatives

2009 ◽  
Vol 121 (10) ◽  
pp. 1862-1865 ◽  
Author(s):  
Chris E. Houlden ◽  
Marc Hutchby ◽  
Chris D. Bailey ◽  
J. Gair Ford ◽  
Simon N. G. Tyler ◽  
...  
Keyword(s):  
Room Temperature ◽  
Aniline Derivatives ◽  
Palladium Catalyzed

Palladium‐Catalyzed Decarbonylative Difluoromethylation of Acid Chlorides at Room Temperature

2018 ◽  
Vol 57 (51) ◽  
pp. 16871-16876 ◽  
Author(s):  
Fei Pan ◽  
Gregory B. Boursalian ◽  
Tobias Ritter
Keyword(s):  
Room Temperature ◽  
Acid Chlorides ◽  
Palladium Catalyzed

Palladium-Catalyzed One-Pot Stereospecific Synthesis of 2-Deoxy Aryl C-Glycosides from Glycals and Anilines in the Presence of tert-Butyl Nitrite

Synthesis ◽  
2019 ◽  
Vol 51 (22) ◽  
pp. 4215-4230 ◽  
Author(s):  
Adesh Kumar Singh ◽  
Rapelly Venkatesh ◽  
Jeyakumar Kandasamy
Keyword(s):  
Room Temperature ◽  
Stereospecific Synthesis ◽  
One Pot ◽  
Tert Butyl ◽  
Mild Conditions ◽  
One Pot Synthesis ◽  
Palladium Catalyzed ◽  
Aryl Glycosides

The palladium-catalyzed one-pot synthesis of 2,3-deoxy-3-keto aryl C-glycosides is achieved from glycals and anilines in the presence of tert-butyl nitrite and aqueous HBF4 under mild conditions. This one-pot method stereospecifically provides α- and β-aryl glycosides (≥19:1 by NMR) in good yields at room temperature. The configuration at the C-3 position in the glycal determines the anomeric selectivity (i.e., α or β) of the desired products.

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