Palladium-catalyzed Mizoroki–Heck-type reactions of [Ph2SRfn][OTf] with alkenes at room temperature

2016 ◽  
Vol 52 (80) ◽  
pp. 11893-11896 ◽  
Author(s):  
Shi-Meng Wang ◽  
Hai-Xia Song ◽  
Xiao-Yan Wang ◽  
Nan Liu ◽  
Hua-Li Qin ◽  
...  
Keyword(s):  
Room Temperature ◽  
Cross Coupling ◽  
Palladium Catalyzed

The first Pd-catalyzed Mizoroki–Heck-type cross-coupling of phenylsulfonium salts with alkenes was disclosed at room temperature.

Room Temperature Palladium-Catalyzed Cross Coupling of Aryltrimethylammonium Triflates with Aryl Grignard Reagents

2010 ◽  
Vol 12 (19) ◽  
pp. 4388-4391 ◽  
Author(s):  
Jonathan T. Reeves ◽  
Daniel R. Fandrick ◽  
Zhulin Tan ◽  
Jinhua J. Song ◽  
Heewon Lee ◽  
...  
Keyword(s):  
Room Temperature ◽  
Cross Coupling ◽  
Grignard Reagents ◽  
Palladium Catalyzed

scholarly journals Palladium-Catalyzed Room Temperature Acylative Cross-Coupling of Activated Amides with Trialkylboranes

Molecules ◽  
2018 ◽  
Vol 23 (10) ◽  
pp. 2412 ◽  
Author(s):  
Weijia Shi ◽  
Gang Zou
Keyword(s):  
Functional Groups ◽  
Room Temperature ◽  
Cross Coupling ◽  
Methyl Tert Butyl Ether ◽  
Palladium Chloride ◽  
Butyl Ether ◽  
Good Tolerance ◽  
Palladium Catalyzed ◽  
Supported Palladium

A highly efficient acylative cross-coupling of trialkylboranes with activated amides has been effected at room temperature to give the corresponding alkyl ketones in good to excellent yields by using 1,3-bis(2,6-diisopropyl)phenylimidazolylidene and 3-chloropyridine co-supported palladium chloride, the PEPPSI catalyst, in the presence of K2CO3 in methyl tert-butyl ether. The scope and limitations of the protocol were investigated, showing good tolerance of acyl, cyano, and ester functional groups in the amide counterpart while halo group competed via the classical Suzuki coupling. The trialkylboranes generated in situ by hydroboration of olefins with BH3 or 9-BBN performed similarly to those separately prepared, making this protocol more practical.

ChemInform Abstract: Room-Temperature Palladium-Catalyzed Cross-Coupling of Aryltrimethylammonium Triflates with Aryl Grignard Reagents.

ChemInform ◽  
2011 ◽  
Vol 42 (7) ◽  
pp. no-no
Author(s):  
Jonathan T. Reeves ◽  
Daniel R. Fandrick ◽  
Zhulin Tan ◽  
Jinhua J. Song ◽  
Heewon Lee ◽  
...  
Keyword(s):  
Room Temperature ◽  
Cross Coupling ◽  
Grignard Reagents ◽  
Palladium Catalyzed
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