Water-Soluble Imine Ligand/Palladium-Catalyzed Suzuki Reaction at Room Temperature

2010 ◽  
Vol 31 (10) ◽  
pp. 1277-1280
Author(s):  
Chun LIU ◽  
Qijian NI ◽  
Pingping HU ◽  
Hao YUAN ◽  
Zilin JIN
Keyword(s):  
Room Temperature ◽  
Suzuki Reaction ◽  
Water Soluble ◽  
Palladium Catalyzed

Synthesis of PEG-supported organotrifluoroborates and their applications in palladium-catalyzed homo-coupling reactions

2015 ◽  
Vol 44 (10) ◽  
pp. 4759-4764
Author(s):  
Li Yong ◽  
Min-Liang Yao ◽  
David W. Blevins ◽  
George W. Kabalka
Keyword(s):  
Room Temperature ◽  
Water Soluble ◽  
Coupling Reactions ◽  
Synthetic Route ◽  
Palladium Catalyzed

A general synthetic route to water-soluble PEG-supported organotrifluoroborates has been developed. In the presence of air and catalytic amounts of Pd(OAc)2, the PEG-supported organotrifluoroborates undergo homo-coupling reactions smoothly at room temperature.

Tyrosine-Selective Bioconjugation with Iminoxyl Radicals

2020 ◽  
Author(s):  
Katsuya Maruyama ◽  
Takashi Ishiyama ◽  
Yohei Seki ◽  
Kounosuke Oisaki ◽  
Motomu Kanai
Keyword(s):  
Reaction Time ◽  
Steric Hindrance ◽  
Room Temperature ◽  
Water Soluble ◽  
Light Irradiation ◽  
Sodium Ascorbate ◽  
Iminoxyl Radical ◽  
Short Reaction Time ◽  
Modified Peptides ◽  
The Stability

A novel Tyr-selective protein bioconjugation using the water-soluble persistent iminoxyl radical is described. The conjugation proceeded with high Tyr-selectivity and short reaction time under biocompatible conditions (room temperature in buffered media under air). The stability of the conjugates was tunable depending on the steric hindrance of iminoxyl. The presence of sodium ascorbate and/or light irradiation promoted traceless deconjugation, restoring the native Tyr structure. The method is applied to the synthesis of a protein-dye conjugate and further derivatization to azobenzene-modified peptides.

Palladium-Catalyzed Suzuki Reaction Using a New N-Carbazolyl Di-phosphine

2011 ◽  
Vol 31 (12) ◽  
pp. 1478-1482
Author(s):  
Zonghai PENG ◽  
Haiyan FU ◽  
Menglin MA ◽  
Hua CHEN ◽  
Xianjun LI
Keyword(s):  
Suzuki Reaction ◽  
Palladium Catalyzed

Dynamics of Anthracene Excimer Formation within a Water-Soluble Nanocavity at Room Temperature

2021 ◽  
Vol 143 (4) ◽  
pp. 2025-2036
Author(s):  
Aritra Das ◽  
Ashwini Danao ◽  
Shubhojit Banerjee ◽  
A. Mohan Raj ◽  
Gaurav Sharma ◽  
...  
Keyword(s):  
Room Temperature ◽  
Water Soluble ◽  
Excimer Formation

Palladium‐Catalyzed C‐C Bond Activation/Suzuki Reaction of Methylenecyclobutanes †

2021 ◽  
Author(s):  
Xiao‐Bing Chen ◽  
Li Li ◽  
Wan‐Chun Yang ◽  
Kun‐Long Song ◽  
Bin Wu ◽  
...  
Keyword(s):  
Bond Activation ◽  
Suzuki Reaction ◽  
Palladium Catalyzed
Sign in / Sign up

Export Citation Format

Share Document