ChemInform Abstract: Regioselective Ring Opening of Epoxides Using NH4SCN/Silica Sulfuric Acid: An Efficient Approach for the Synthesis of β-Hydroxy Thiocyanate under Solvent-Free Conditions.

ChemInform ◽  
2008 ◽  
Vol 39 (46) ◽  
Author(s):  
Ali R. Kiasat ◽  
Maryam Zayadi ◽  
Mehdi Fallah Mehrjardi
Keyword(s):  
Sulfuric Acid ◽  
Ring Opening ◽  
Solvent Free ◽  
Silica Sulfuric Acid ◽  
Efficient Approach ◽  
Solvent Free Conditions ◽  
Ring Opening Of Epoxides

ChemInform Abstract: Silica Sulfuric Acid Mediated Acylation of Amines with 1,3-Diketones via C-C Bond Cleavage under Solvent-Free Conditions.

ChemInform ◽  
2016 ◽  
Vol 47 (8) ◽  
pp. no-no
Author(s):  
Ruiqiang Guo ◽  
Chuanlei Zhu ◽  
Zhe Sheng ◽  
Yanzhe Li ◽  
Wei Yin ◽  
...  
Keyword(s):  
Sulfuric Acid ◽  
Bond Cleavage ◽  
Solvent Free ◽  
Silica Sulfuric Acid ◽  
Solvent Free Conditions

scholarly journals Silica sulfuric acid: a reusable solid catalyst for one pot synthesis of densely substituted pyrrole-fused isocoumarins under solvent-free conditions

2013 ◽  
Vol 9 ◽  
pp. 2344-2353 ◽  
Author(s):  
Sudipta Pathak ◽  
Kamalesh Debnath ◽  
Animesh Pramanik
Keyword(s):  
Sulfuric Acid ◽  
Low Cost ◽  
Solvent Free ◽  
Primary Amines ◽  
Solid Catalyst ◽  
Silica Sulfuric Acid ◽  
Reaction Conditions ◽  
One Pot ◽  
Solvent Free Conditions ◽  
Solvent Free Reaction

A convenient and efficient methodology for the synthesis of densely substituted pyrrole-fused isocoumarins, which employs solid-supported silica sulfuric acid (SSA) as catalyst, has been developed. When the mixture of ninhydrin adducts of acetylacetone/ethyl acetoacetate and primary amines was heated on the solid surface of SSA under solvent-free conditions, the pyrrole-fused isocoumarins were formed in good yields. This synthetic method has several advantages such as the employment of solvent-free reaction conditions without the use of any toxic reagents and metal catalysts, the ease of product isolation, the use of a recyclable catalyst, the low cost, the easy availability of the starting materials, and the excellent yields of products.

Solid lithium perchlorate as a powerful catalyst for the synthesis of β-aminoalcohols under solvent-free conditions

2005 ◽  
Vol 83 (5) ◽  
pp. 505-507 ◽  
Author(s):  
Najmodin Azizi ◽  
Mohammad R Saidi
Keyword(s):  
Ring Opening ◽  
Room Temperature ◽  
Lithium Perchlorate ◽  
Solvent Free ◽  
Solvent Free Conditions ◽  
Reaction Proceeds ◽  
Ring Opening Of Epoxides ◽  
Neutral Conditions ◽  
Hindered Amines ◽  
Short Times

Lithium perchlorate catalyzed the ring opening of epoxides with amines to provide the corresponding β-aminoalcohols in excellent yields with high regioselectivity. The reaction proceeds rapidly under mild and neutral conditions and worked well with primary, secondary, aliphatic, aromatic, and hindered amines in short times at room temperature, in the absence of solvent.Key words: epoxide, lithium perchlorate, β-aminoalcohols, solvent-free.

scholarly journals N-Formylation of Anilines with Silica Sulfuric Acid under Solvent-Free Conditions

2013 ◽  
Vol 2013 ◽  
pp. 1-6 ◽  
Author(s):  
Davood Habibi ◽  
Payam Rahmani ◽  
Ziba Akbaripanah
Keyword(s):  
Sulfuric Acid ◽  
Formic Acid ◽  
Reaction Times ◽  
Solvent Free ◽  
Secondary Amines ◽  
Silica Sulfuric Acid ◽  
Excellent Yield ◽  
Solvent Free Conditions ◽  
Primary And Secondary Amines

N-formylation of primary and secondary amines was carried out with formic acid in the presence of silica sulfuric acid under solvent-free conditions to give the corresponding formamides in excellent yield and short reaction times.

Efficient method for ring opening of epoxides with amines by NaY zeolite under solvent-free conditions

2007 ◽  
Vol 264 (1-2) ◽  
pp. 162-169 ◽  
Author(s):  
Rukhsana Ilyas Kureshy ◽  
Surendra Singh ◽  
Noor-ul Hasan Khan ◽  
Sayed Hasan Razi Abdi ◽  
Eringathodi Suresh ◽  
...  
Keyword(s):  
Efficient Method ◽  
Ring Opening ◽  
Solvent Free ◽  
Nay Zeolite ◽  
Solvent Free Conditions ◽  
Ring Opening Of Epoxides

Silica sulfuric acid as an efficient and recyclable catalyst for the methoxymethylation of alcohols under solvent-free conditions

2006 ◽  
Vol 7 (7) ◽  
pp. 494-498 ◽  
Author(s):  
Khodabakhsh Niknam ◽  
Mohammad Ali Zolfigol ◽  
Ahmad Khorramabadi-Zad ◽  
Reza Zare ◽  
Mohsen Shayegh
Keyword(s):  
Sulfuric Acid ◽  
Recyclable Catalyst ◽  
Solvent Free ◽  
Silica Sulfuric Acid ◽  
Solvent Free Conditions
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