The influence of ligand chirality on the self-assembly and spectroscopic properties of copper(i) halide coordination polymers was investigated.
Structural, solid state luminescence of Cd(ii) coordination polymers and detection of acetone by CP1via luminescence quenching have been discussed.
The self-assembly of d10 metal salts and two racemic bis(pyridyl) diamine ligands generates ten complexes, showing diverse helical and wavelike chains, (4,4) layers, as well as 3D sqc and uog nets.
Remarkable differences in the physicochemical properties of metal–organic gels of Fe(iii) and Al(iii) ions with the TCA ligand is reported.