A series of helical coordination polymers based on two racemic bis(pyridylmethylene) propane-1,2-diamine ligands: relationship of conformations, structures and properties

The self-assembly of d10 metal salts and two racemic bis(pyridyl) diamine ligands generates ten complexes, showing diverse helical and wavelike chains, (4,4) layers, as well as 3D sqc and uog nets.

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Copper(i) halide cluster-based coordination polymers modulated by chiral ditopic dithiodianthranilide ligands: synthesis, crystal structure and photoluminescence

CrystEngComm ◽

10.1039/d0ce01589j ◽

2021 ◽

Author(s):

Jarosław Chojnacki ◽

Michał Mońka ◽

Illia E. Serdiuk ◽

Piotr Bojarski ◽

Tadeusz Połoński ◽

...

Keyword(s):

Crystal Structure ◽

Coordination Polymers ◽

Self Assembly ◽

Spectroscopic Properties ◽

The Self ◽

Halide Cluster

The influence of ligand chirality on the self-assembly and spectroscopic properties of copper(i) halide coordination polymers was investigated.

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Hydrothermal Syntheses, Crystal Structures, and Luminescent Properties of Two MnII Coordination Polymers: From Two-Fold Interpenetrated pcu Topological Net to Polycatenated 2D+2D→3D Framework

Australian Journal of Chemistry ◽

10.1071/ch14092 ◽

2015 ◽

Vol 68 (2) ◽

pp. 322 ◽

Cited By ~ 2

Author(s):

Wenlong Liu ◽

Mengqiang Wu ◽

Xueying Wang ◽

Wei Wang ◽

Dayu Liu ◽

...

Keyword(s):

Dicarboxylic Acid ◽

Coordination Polymers ◽

Self Assembly ◽

Room Temperature ◽

Luminescent Properties ◽

The Self ◽

X Ray Diffraction ◽

X Ray ◽

3D Framework ◽

Dimethyl Benzene

Using a hydrothermal synthesis, the self-assembly of MnII ions and 1,4-bis(1-imidazol-yl)-2,5-dimethyl benzene with two dicarboxylate ligands, 2-nitrobenzene-1,4-dicarboxylic acid (2-H2ata) and 5-methylbenzene-1,3-dicarboxylic acid (5-CH3-H2ip) constructed two interesting coordination polymers: [Mn(2-ata)(bimb)]n (1) and {[Mn(5-CH3-ip)(bimb)1.5]·2H2O}n (2), where bimb refers to 1,4-bis(1-imidazol-yl)-2,5-dimethyl benzene. Their structures were determined by single-crystal X-ray diffraction, elemental analysis, and infrared spectroscopy. Complex 1 exhibits a 2-fold interpenetrated pcu net. Complex 2 shows an unusual polycatenated 2D+2D→3D framework. In addition, the solid-state photoluminescent properties of 1 and 2 were investigated at room temperature.

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Coordination polymers from mild condition reactions of copper(II) carboxylates with pyrazole (Hpz). Influence of carboxylate basicity on the self-assembly of the [Cu3(μ3-OH)(μ-pz)3]2+ secondary building unit

Inorganica Chimica Acta ◽

10.1016/j.ica.2016.05.009 ◽

2017 ◽

Vol 455 ◽

pp. 618-626 ◽

Cited By ~ 10

Author(s):

Sara Massignani ◽

Rebecca Scatena ◽

Arianna Lanza ◽

Magda Monari ◽

Francesca Condello ◽

...

Keyword(s):

Coordination Polymers ◽

Mild Condition ◽

Self Assembly ◽

The Self ◽

Secondary Building Unit ◽

Building Unit

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Effect of Anions on the Self-Assembly of Cd(II)-Containing Coordination Polymers Based on a Novel Flexible Tetrakis(imidazole) Ligand

Crystal Growth & Design ◽

10.1021/cg901332m ◽

2010 ◽

Vol 10 (2) ◽

pp. 995-1016 ◽

Cited By ~ 132

Author(s):

Hong-Ye Bai ◽

Jian-Fang Ma ◽

Jin Yang ◽

Ying-Ying Liu ◽

Hua-Wu ◽

...

Keyword(s):

Coordination Polymers ◽

Self Assembly ◽

The Self ◽

Imidazole Ligand

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Influence of the central metal ion in controlling the self-assembly and magnetic properties of 2D coordination polymers derived from [(NiL)2M]2+ nodes (M = Ni, Zn and Cd) (H2L = salen-type di-Schiff base) and dicyanamide spacers

Dalton Transactions ◽

10.1039/c4dt02823f ◽

2015 ◽

Vol 44 (3) ◽

pp. 1292-1302 ◽

Cited By ~ 20

Author(s):

Lakshmi Kanta Das ◽

Carlos J. Gómez-García ◽

Ashutosh Ghosh

Keyword(s):

Magnetic Properties ◽

Schiff Base ◽

Coordination Polymers ◽

Self Assembly ◽

Significant Variation ◽

Metal Ion ◽

The Self ◽

Central Metal

Three new 2D coordination polymers of different networks with significant variation in magnetic properties have been synthesized by changing the central metal in the trinuclear nodes.

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Porphyrin-based metal coordination polymers with self-assembly pathway-dependent properties for photodynamic and photothermal therapy

10.21203/rs.3.rs-54280/v1 ◽

2020 ◽

Author(s):

Yuyang Miao ◽

Shibo Lv ◽

Daoyuan Zheng ◽

Yuhan Liu ◽

Dapeng Liu ◽

...

Keyword(s):

Coordination Polymers ◽

Self Assembly ◽

Photothermal Therapy ◽

The Self ◽

Metal Coordination ◽

Great Promise ◽

Assembly Process ◽

Assembly Pathway ◽

Metal Organic ◽

Metal Coordination Polymers

Abstract Porphyrin-based metal coordination polymers (MCPs) have attracted numerous attention due to their great promise application in phototherapy including photodynamic therapy (PDT) and photothermal therapy (PTT). However, the detailed self-assembly process of porphyrin-based MCPs still remains poorly understood. This work provides a detailed study of the self-assembly process of MCPs constructed by Mn2+ and TCPP (TCPP: 4,4′,4′′,4′′′-(Porphine-5,10,15,20-tetrayl)tetrakis(benzoic acid)) in aqueous solution. Unlike traditional nucleation and growth mechanism, we discover that there is a metastable metal-organic intermediate which is kinetically favored in the self-assembly process. And the metastable metal-organic intermediate nanotape structures could convert into thermodynamically favored nanosheets through disassembling into monomers followed by reassembling process. Moreover, the two structurally different assemblies exhibit distinct photophysical performances. The intermediate Mn-TCPP aggregates show good light-induced singlet oxygen 1O2 generation for PDT while the thermodynamic favored stable Mn-TCPP aggregates exhibit good photothermal conversion ability as photothermal agents (PTAs). This study could facilitate controlling self-assembly pathway to fabricate complex MCPs with desirable applications.

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Self-assembly of an Organometallic Fe9O6 Cluster from Aerobic Oxidation of (tmeda)Fe(CH2tBu)2

10.26434/chemrxiv.9479711.v1 ◽

2019 ◽

Author(s):

Jonathan Kephart ◽

Zachary Hecht ◽

Brooke N. Livesay ◽

Matthew P. Shores ◽

V. Codrina Popescu ◽

...

Keyword(s):

Solid State ◽

High Spin ◽

Self Assembly ◽

Organometallic Compound ◽

Aerobic Oxidation ◽

The Self ◽

Ferrous Oxide ◽

Antiferromagnetic Coupling ◽

Oxide Cluster ◽

Diamine Ligands

<div><div><div><p>Substoichiometric aerobic oxidation of the high-spin organometallic compound (tmeda)Fe(CH2tBu)2 (tmeda = N,N,N’,N’- tetramethylethylenediamine) in toluene or THF solution leads to the self-assembly of a magic-sized all-ferrous oxide cluster containing the Fe9O6 subunit and bearing organometallic and diamine ligands. Mössbauer studies of the cluster and the reference complex (tmeda)Fe(OCPh3)2 are consistent with the all-ferrous assignment, and magnetometry reveal considerable antiferromagnetic coupling between Fe atoms in the cluster and frustrated antiferromagnetic interactions between clusters in the solid state.</p></div></div></div>

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Syntheses, Crystal Structures and Properties of Two New Manganese(II) Coordination Polymers with Tetrafluorophthalate Ligands

Zeitschrift für Naturforschung B ◽

10.5560/znb.2013-3022 ◽

2013 ◽

Vol 68 (3) ◽

pp. 277-283 ◽

Cited By ~ 2

Author(s):

Sheng-Chun Chen ◽

Jing Qin ◽

Zhi-Hui Zhang ◽

Xiao-Xiao Cai ◽

Jian Gao ◽

...

Keyword(s):

Solid State ◽

Ir Spectroscopy ◽

Self Assembly ◽

The Self ◽

Photoluminescence Properties ◽

Double Chain ◽

Triclinic Space Group ◽

One Dimensional ◽

Structures And Properties ◽

Supramolecular Networks

Two new polymeric MnII complexes, {[Mn(1,2-BDC-F4)(H2O)3](EtOH)}n (1) and [Mn(1,2- BDC-F4)(H2O)2(DMF)]n (2), have been prepared from the reaction of MnII acetate with 3,4,5,6- tetrafluoro-benzene-1,2-dicarboxylic acid (1,2-H2BDC-F4) using different solvents, and characterized by elemental analysis, IR spectroscopy, thermogravimetric (TG) analysis, and single-crystal Xray structure analysis. Both complexes crystallize in the triclinic space group P1̄ and have similar one-dimensional double chain structures, consisting of a unique arrangement of 8-membered and 14- membered rings. The effects of solvent as ligand and/or guest on the self-assembly processes of the supramolecular networks and on their photoluminescence properties in the solid state are discussed.

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