The Origin of Molecular Mobility During Biomass Pyrolysis as Revealed by In situ 1H NMR Spectroscopy

ChemSusChem ◽  
2012 ◽  
Vol 5 (7) ◽  
pp. 1258-1265 ◽  
Author(s):  
Anthony Dufour ◽  
Miguel Castro-Diaz ◽  
Nicolas Brosse ◽  
Mohamed Bouroukba ◽  
Colin Snape
1986 ◽  
Vol 155 (1) ◽  
pp. 38-44 ◽  
Author(s):  
Jamie I. Vandenberg ◽  
Philip W. Kuchel ◽  
Glenn K. King

1992 ◽  
Vol 267 (14) ◽  
pp. 9905-9910
Author(s):  
R.A. Kauppinen ◽  
T Nissinen ◽  
A.M. Kärkkäinen ◽  
T.R. Pirttilä ◽  
J Palvimo ◽  
...  

LWT ◽  
2021 ◽  
Vol 145 ◽  
pp. 111296
Author(s):  
Claudio Cassino ◽  
Christos Tsolakis ◽  
Federica Gulino ◽  
Enrico Vaudano ◽  
Domenico Osella

2008 ◽  
Vol 181 (1) ◽  
pp. 116-119 ◽  
Author(s):  
Jian Zhi Hu ◽  
Ja Hun Kwak ◽  
Zhenguo Yang ◽  
William Osborn ◽  
Tippawan Markmaitree ◽  
...  

2008 ◽  
Vol 59 (7) ◽  
Author(s):  
Maria Maganu ◽  
Filip Chiraleu ◽  
Constantin Draghici ◽  
Gheorghe Mihai

The previous data obtained by 1H-NMR spectroscopy established the existence of an asymmetry of the bond between Pd and p-allylic groups, even in the p-allyl-Pd complexes dimers which are considered usually symmetric dimers. The asymmetry of the bond depends by the substitutes of the allylic group. Other analytical methods were investigated for additional proof of the obtained results. Thus, this paper discusses how this asymmetry would be reflected in the infrared spectra and in the reaction of the complexes with carbon monoxide.


2008 ◽  
Vol 59 (10) ◽  
Author(s):  
Paul Ionut Dron ◽  
Neculai Doru Miron ◽  
Gheorghe Surpateanu

The paper presents the synthesis of cyclo (bis-paraquat p-phenylene p-phenylene-carbonyl) tetrakis (hexafluorophosphate), named �CETOBOX�, and the closely related structural determinations. This compound exists in three tautomeric forms. These forms were evidentiated by NMR-data (1H-NMR, TOCSY, COSY, NOESY), UV-Vis spectra coupled with pH measurements and by synthesis. As the �CETOBOX� gives �in situ� only the corresponding monoylide, the synthesis of a new fluorescent indolizine cyclophane has been performed by a 3+2 cycloaddition. All structures of the new compounds presented herein have been established by NMR spectroscopy. Also, theoretical methods (MM3, AM1, AM1-COSMO and B88LYPDFT) have been used to determine the most stable conformer structures.


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