Homogeneous Water Oxidation Catalyzed by First‐Row Transition Metal Complexes: Unveiling the Relationship between Turnover Frequency and Reaction Overpotential

ChemSusChem ◽  
2021 ◽  
Author(s):  
Yu-Heng Wang ◽  
Wan-Chi Hsu
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Water Oxidation ◽  
Turnover Frequency ◽  
The Relationship

scholarly journals Photocatalytic production of hydrogen peroxide from water and dioxygen using cyano-bridged polynuclear transition metal complexes as water oxidation catalysts

2016 ◽  
Vol 6 (3) ◽  
pp. 681-684 ◽  
Author(s):  
Yusuke Isaka ◽  
Kohei Oyama ◽  
Yusuke Yamada ◽  
Tomoyoshi Suenobu ◽  
Shunichi Fukuzumi
Keyword(s):  
Hydrogen Peroxide ◽  
Transition Metal ◽  
Visible Light ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Visible Light Irradiation ◽  
Water Oxidation ◽  
Light Irradiation ◽  
Oxidation Catalysts ◽  
Production Of Hydrogen

H2O2 was produced from H2O and O2 using cyano-bridged polynuclear transition metal complexes as water oxidation catalysts with a Ru photocatalyst in water under visible light irradiation.

Cycloaddition of CO2 to epoxides using di-nuclear transition metal complexes as catalysts

2016 ◽  
Vol 40 (6) ◽  
pp. 4974-4980 ◽  
Author(s):  
Mohmmad Y. Wani ◽  
Santosh Kumar ◽  
Claudia T. Arranja ◽  
Carlos M. F. Dias ◽  
Abilio J. F. N. Sobral
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Catalyst System ◽  
Ni Catalyst ◽  
Nuclear Transition ◽  
Turnover Frequency ◽  
High Turnover

Cycloaddition of CO2 to epoxides was carried out selectively using di-nuclear Cu(ii), Co(ii) or Ni(ii)/n-Bu4NI catalyst system with high turnover frequency.

Mechanochemical changes on cyclometalated Ir(iii) acyclic carbene complexes – design and tuning of luminescent mechanochromic transition metal complexes

2020 ◽  
Vol 7 (3) ◽  
pp. 786-794 ◽  
Author(s):  
Jingqi Han ◽  
Kin-Man Tang ◽  
Shun-Cheung Cheng ◽  
Chi-On Ng ◽  
Yuen-Kiu Chun ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Carbene Complexes ◽  
New Class

A new class of luminescent cyclometalated Ir(iii) complexes with readily tunable mechanochromic properties derived from the mechanically induced trans-to-cis isomerization have been developed.

Density Functional Calculations of EPR Parameter g Tensors of Some Transition Metal Complexes

2011 ◽  
Vol 2 (2) ◽  
pp. 139-141
Author(s):  
Vinita Prajapati ◽  
◽  
P.L.Verma P.L.Verma ◽  
Dhirendra Prajapati ◽  
B.K.Gupta B.K.Gupta
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Density Functional Calculations ◽  
Density Functional
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