Promoted hydrogenolysis of furan aldehydes to dimethylfuran by a defect engineering on Pd/NiCo2O4

ChemSusChem ◽  
2022 ◽  
Author(s):  
Xiang Li ◽  
Likang Zhang ◽  
Qiang Deng ◽  
Shixia Chen ◽  
Jun Wang ◽  
...  
Keyword(s):  
Defect Engineering

Engineering Porosity Through Defects in a Giant Pore Metal–Organic Framework

2020 ◽  
Author(s):  
Adam Sapnik ◽  
Duncan Johnstone ◽  
Sean M. Collins ◽  
Giorgio Divitini ◽  
Alice Bumstead ◽  
...  
Keyword(s):  
Distribution Function ◽  
Ball Milling ◽  
Local Structure ◽  
Pair Distribution Function ◽  
Function Analysis ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Defect Engineering ◽  
Metal Organic ◽  
Unsaturated Metal Sites

<p>Defect engineering is a powerful tool that can be used to tailor the properties of metal–organic frameworks (MOFs). Here, we incorporate defects through ball milling to systematically vary the porosity of the giant pore MOF, MIL-100 (Fe). We show that milling leads to the breaking of metal–linker bonds, generating more coordinatively unsaturated metal sites, and ultimately causes amorphisation. Pair distribution function analysis shows the hierarchical local structure is partially</p><p>retained, even in the amorphised material. We find that the solvent toluene stabilises the MIL-100 (Fe) framework against collapse and leads to a substantial rentention of porosity over the non-stabilised material.</p>

Defect engineering in SiC technology for high-voltage power devices

2020 ◽  
Vol 13 (12) ◽  
pp. 120101
Author(s):  
Tsunenobu Kimoto ◽  
Heiji Watanabe
Keyword(s):  
High Voltage ◽  
Defect Engineering ◽  
Power Devices

Universal Approach toward Hysteresis-Free Perovskite Solar Cell via Defect Engineering

2018 ◽  
Vol 140 (4) ◽  
pp. 1358-1364 ◽  
Author(s):  
Dae-Yong Son ◽  
Seul-Gi Kim ◽  
Ja-Young Seo ◽  
Seon-Hee Lee ◽  
Hyunjung Shin ◽  
...  
Keyword(s):  
Solar Cell ◽  
Perovskite Solar Cell ◽  
Defect Engineering ◽  
Universal Approach

Strategic Defect Engineering of Metal‐Organic Frameworks for Optimizing the Fabrication of Single‐Atom Catalysts

2021 ◽  
pp. 2103597
Author(s):  
Jie He ◽  
Na Li ◽  
Zhi‐Gang Li ◽  
Ming Zhong ◽  
Zi‐Xuan Fu ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Single Atom ◽  
Defect Engineering ◽  
Metal Organic

Defect engineering and characterization of active sites for efficient electrocatalysis

Nanoscale ◽  
2021 ◽  
Vol 13 (6) ◽  
pp. 3327-3345
Author(s):  
Xuecheng Yan ◽  
Linzhou Zhuang ◽  
Zhonghua Zhu ◽  
Xiangdong Yao
Keyword(s):  
Transition Metal ◽  
Active Sites ◽  
Defect Engineering ◽  
Metal Free

This review highlights recent advancements in defect engineering and characterization of both metal-free carbons and transition metal-based electrocatalysts.

Defect Engineering on a Ti4O7 Electrode by Ce3+ Doping for the Efficient Electrooxidation of Perfluorooctanesulfonate

2021 ◽  
Vol 55 (4) ◽  
pp. 2597-2607
Author(s):  
Hui Lin ◽  
Runlin Xiao ◽  
Ruzhen Xie ◽  
Lihui Yang ◽  
Caiming Tang ◽  
...  
Keyword(s):  
Defect Engineering

Facile defect engineering in ZnIn2S4 coupled with carbon dots for rapid diclofenac degradation

2020 ◽  
Author(s):  
Dongxu Yang ◽  
Jialiang Liang ◽  
Liang Luo ◽  
Ruoyu Deng ◽  
Guo Li ◽  
...  
Keyword(s):  
Carbon Dots ◽  
Defect Engineering

scholarly journals Defect and Doping Co-Engineered Non-Metal Nanocarbon ORR Electrocatalyst

2021 ◽  
Vol 13 (1) ◽  
Author(s):  
Jian Zhang ◽  
Jingjing Zhang ◽  
Feng He ◽  
Yijun Chen ◽  
Jiawei Zhu ◽  
...  
Keyword(s):  
Rational Design ◽  
Low Cost ◽  
Reduction Reaction ◽  
Defect Engineering ◽  
Heteroatom Doping ◽  
Competitive Activity ◽  
Design And Manufacturing ◽  
Earth Abundant ◽  
Induced Defects ◽  
Carbon Based

AbstractExploring low-cost and earth-abundant oxygen reduction reaction (ORR) electrocatalyst is essential for fuel cells and metal–air batteries. Among them, non-metal nanocarbon with multiple advantages of low cost, abundance, high conductivity, good durability, and competitive activity has attracted intense interest in recent years. The enhanced ORR activities of the nanocarbons are normally thought to originate from heteroatom (e.g., N, B, P, or S) doping or various induced defects. However, in practice, carbon-based materials usually contain both dopants and defects. In this regard, in terms of the co-engineering of heteroatom doping and defect inducing, we present an overview of recent advances in developing non-metal carbon-based electrocatalysts for the ORR. The characteristics, ORR performance, and the related mechanism of these functionalized nanocarbons by heteroatom doping, defect inducing, and in particular their synergistic promotion effect are emphatically analyzed and discussed. Finally, the current issues and perspectives in developing carbon-based electrocatalysts from both of heteroatom doping and defect engineering are proposed. This review will be beneficial for the rational design and manufacturing of highly efficient carbon-based materials for electrocatalysis.

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