Palladium-catalyzed oxidative desymmetrization enables the efficient synthesis of both enantioenriched cycloalkenone building blocks and diverse epoxyquinoid natural products.
An efficient synthesis of diarylalkynes was achieved from the domino cross-coupling reaction of 1,1-dichloroalkenes with triarylbismuth reagents under palladium-catalyzed conditions.
An efficient [3+1+1] cyclization of vinyl oxiranes for the synthesis of oxazolidinones has been developed via tandem palladium catalysis. This reaction provides a atom- and step-efficient strategy to produce oxazolidinones...