Effect of Nickel Precursor on the Catalytic Performance of Graphene Aerogel‐Supported Nickel Nanoparticles for the Production of CO x ‐free Hydrogen by Ammonia Decomposition

2021 ◽  
Author(s):  
Tolga Kocer ◽  
F. Eylül Saraç-Öztuna ◽  
Samira Fatma Kurtoğlu-Öztulum ◽  
Ugur Unal ◽  
Alper Uzun
2018 ◽  
Vol 54 (49) ◽  
pp. 6364-6367 ◽  
Author(s):  
Yanping Li ◽  
Jie Wen ◽  
Arshid M. Ali ◽  
Ming Duan ◽  
Wei Zhu ◽  
...  

Size structure–catalytic performance correlation was investigated with supported Ni/MCF-17 catalysts over COx-free hydrogen production via the ammonia decomposition reaction.


2014 ◽  
Vol 2 (24) ◽  
pp. 9185-9192 ◽  
Author(s):  
Gang Li ◽  
Hiroki Nagasawa ◽  
Masakoto Kanezashi ◽  
Tomohisa Yoshioka ◽  
Toshinori Tsuru

Support-dependent and structure-sensitive Ru supported by graphene showed an easily controllable nanoarchitecture, yielding drastically improved catalytic performance for ammonia decomposition.


2021 ◽  
Author(s):  
Yingqiu Gu ◽  
Di Xu ◽  
Yun Huang ◽  
Zhouyang Long ◽  
Guojian Chen

Transition metals have been considered as potential catalysts for ammonia decomposition to produce COx-free hydrogen for fuel cells. However, the facile synthesis of transition metal catalyst with small size active...


2016 ◽  
Vol 2016 (21) ◽  
pp. 3469-3473 ◽  
Author(s):  
Daeho Kim ◽  
Hyuntae Kang ◽  
Hyesu Park ◽  
Sungkyun Park ◽  
Ji Chan Park ◽  
...  

Molecules ◽  
2022 ◽  
Vol 27 (2) ◽  
pp. 503
Author(s):  
Qiangu Yan ◽  
Timothy Ketelboeter ◽  
Zhiyong Cai

Nickel (Ni)-lignin nanocomposites were synthesized from nickel nitrate and kraft lignin then catalytically graphitized to few-layer graphene-encapsulated nickel nanoparticles (Ni@G). Ni@G nanoparticles were used for catalytic decomposition of methane (CDM) to produce COx-free hydrogen and graphene nanoplatelets. Ni@G showed high catalytic activity for methane decomposition at temperatures of 800 to 900 °C and exhibited long-term stability of 600 min time-on-stream (TOS) without apparent deactivation. The catalytic stability may be attributed to the nickel dispersion in the Ni@G sample. During the CDM reaction process, graphene shells over Ni@G nanoparticles were cracked and peeled off the nickel cores at high temperature. Both the exposed nickel nanoparticles and the cracked graphene shells may participate the CDM reaction, making Ni@G samples highly active for CDM reaction. The vacancy defects and edges in the cracked graphene shells serve as the active sites for methane decomposition. The edges are continuously regenerated by methane molecules through CDM reaction.


2019 ◽  
Vol 44 (14) ◽  
pp. 7300-7307 ◽  
Author(s):  
Ziqing Wang ◽  
Yingmin Qu ◽  
Xiaolong Shen ◽  
Zhifeng Cai

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