Mixed metal ferrites have shown much promise in two-step solar-thermochemical fuel production. Previous work has typically focused on evaluating a particular metal ferrite produced by a particular synthesis process, which makes comparisons between studies performed by independent researchers difficult. A comparative study was undertaken to explore the effects different synthesis methods have on the performance of a particular material during redox cycling using thermogravimetry. This study revealed that materials made via wet chemistry methods and extended periods of high temperature calcination yield better redox performance. Differences in redox performance between materials made via wet chemistry methods were minimal and these demonstrated much better performance than those synthesized via the solid state method. Subsequently, various metal ferrite samples (NiFe2O4, MgFe2O4, CoFe2O4, and MnFe2O4) in yttria stabilized zirconia (8YSZ) were synthesized via coprecipitation and tested to determine the most promising metal ferrite combination. It was determined that 10 wt.% CoFe2O4in 8YSZ produced the highest and most consistent yields of O2and CO. By testing the effects of synthesis methods and dopants in a consistent fashion, those aspects of ferrite preparation which are most significant can be revealed. More importantly, these insights can guide future efforts in developing the next generation of thermochemical fuel production materials.
Thermodynamic Guiding Principles for Designing Nonstoichiometric Redox Materials for Solar Thermochemical Fuel Production: Ceria, Perovskites, and Beyond
