Eco‐environmental benefits analysis of EcoPartnerships Program of production technology of calcium carbonate from lime mud produced by alkaline papermaking

Author(s):  
Chao Geng ◽  
Tao Ma ◽  
Jianguo Liu
2020 ◽  
Vol 2 (2) ◽  
Author(s):  
Gina Maulia

Recausticizing merupakan proses pengolahan green liquor menjadi white liquor sebagai produk utama dan lumpur kapur (lime mud) sebagai produk samping. Lime mud sebagai produk samping memiliki kandungan CaCO3 yang cukup tinggi sehingga memungkinkan untuk dimanfaatkan menjadi produk yang bernilai jual lebih tinggi. Penelitian ini bertujuan untuk memanfaatkan lime mud sebagai bahan baku pembuatan PCC (Precipitated Calcium Carbonate) yang memiliki nilai jual lebih tinggi. Penelitian pembuatan PCC ini menggunakan metode kaustik soda dengan variasi dosis HNO3 1 M, 3 M, 5 M, 7 M, 9 M, 11 M, dan 12 M kemudian ditambahkan Na2CO3 untuk pembentukan PCC. Berdasarkan hasil penelitian, didapatkan dosis optimum yaitu pada konsentrasi HNO3 12 M dan Na2CO3 2 M dengan nilai rendemen 97.1 % dan kemurnian 99.57 % yang menunjukkan bahwa hasil tersebut sesuai dengan standar PCC.


1992 ◽  
Vol 6 ◽  
pp. 248-248
Author(s):  
L.L. Robbins ◽  
K. Yates

Geologists have long been plagued by the lack of evidence for the origin of ancient micrite deposits: any paleontological evidence is typically obscured or lacking altogether. The role of modern marine picoplankton gives insight into the origin of one mode of lime mud formation and may aid in the interpretation of ancient marine deposits.Whitings, patches of floating lime mud in supersaturated seawater on carbonate platforms, obtained from the Bahama Bank were analyzed utilizing biochemical techniques and Transmission Electron Microscopy. All Whitings indicated a close association between picoplankton cellular material and calcium carbonate crystals. Culture experiments indicated the presence of at least ten different picoplankton species in Whitings water. Two major genera found were the blue-green algae, Synechococcus and Synechocystis. Field and laboratory experimental data indicated that these cells and cellular organics play a major role in Whitings formation. The cells may undergo epicellular precipitation of calcium carbonate induced by photosynthesis. Environmental conditions necessary for this process have been delineated through field data and laboratory experiments.While picoplankton organics are rarely preserved over geologic time, the product of their life habit, namely lime mud, is preserved as micrite. Thick occurrences of micrite deposited in marine environments are widespread throughout the geologic record, ranging in age from Precambrian to Recent. Although rare, fossilized blue-green algae have been observed in Archean rocks and may be the only evidence that implicates these organisms in lime mud formation. The Whitings phenomenon serves as an excellent example in which a specific type of organism may be a prolific contributor to the rock record, and yet leaves no direct paleontological evidence of its involvement.


2019 ◽  
Vol 34 (3) ◽  
pp. 264-270
Author(s):  
Jian Wang ◽  
Yaowei Xu ◽  
Zhijie Wang ◽  
Jianpeng Sun ◽  
Min Liu

Abstract Lime mud (LM) is a by-product originated from the causticization process of papermaking industry. Microscopic structural changes of LM in carbonization process lead to defects on its performance. Regulating the growth of calcium carbonate obtained from the carbonization process and preventing its influence on the surface microstructure of LM has become the key to achieve the self-digestion of this solid waste. In this study, microscopic structural changes of LM co-carbonized with sodium polyacrylate (PAAS) were investigated. The results showed that, compared with traditional carbonation, the microstructure of LM co-carbonized with PAAS was changed remarkably. The newly calcium carbonate formed in the carbonization process would be solidified and coated on the LM surface. Then LM co-carbonized with PAAS would have a smaller specific surface area, pore volume and pore size, which significantly improved its application performance when it was used as paper filler. In addition, a potential technique for improving the surface microstructure of calcium carbonate particle was proposed.


ACS Omega ◽  
2021 ◽  
Vol 6 (5) ◽  
pp. 3884-3890
Author(s):  
Jung Soo Han ◽  
Dong Suk Kang ◽  
Yung Bum Seo
Keyword(s):  

Author(s):  
S. Q. Xiao ◽  
S. Baden ◽  
A. H. Heuer

The avian eggshell is one of the most rapidly mineralizing biological systems known. In situ, 5g of calcium carbonate are crystallized in less than 20 hrs to fabricate the shell. Although there have been much work about the formation of eggshells, controversy about the nucleation and growth mechanisms of the calcite crystals, and their texture in the eggshell, still remain unclear. In this report the microstructure and microchemistry of avian eggshells have been analyzed using transmission electron microscope (TEM) and energy dispersive spectroscopy (EDS).Fresh white and dry brown eggshells were broken and fixed in Karnosky's fixative (kaltitanden) for 2 hrs, then rinsed in distilled H2O. Small speckles of the eggshells were embedded in Spurr medium and thin sections were made ultramicrotome.The crystalline part of eggshells are composed of many small plate-like calcite grains, whose plate normals are approximately parallel to the shell surface. The sizes of the grains are about 0.3×0.3×1 μm3 (Fig.l). These grains are not as closely packed as man-made polycrystalline metals and ceramics, and small gaps between adjacent grains are visible indicating the absence of conventional grain boundaries.


2020 ◽  
pp. 637-656 ◽  
Author(s):  
Marco Medici ◽  
Søren Marcus Pedersen ◽  
Giacomo Carli ◽  
Maria Rita Tagliaventi

The purpose of this study is to analyse the environmental benefits of precision agriculture technology adoption obtained from the mitigation of negative environmental impacts of agricultural inputs in modern farming. Our literature review of the environmental benefits related to the adoption of precision agriculture solutions is aimed at raising farmers' and other stakeholders' awareness of the actual environmental impacts from this set of new technologies. Existing studies were categorised according to the environmental impacts of different agricultural activities: nitrogen application, lime application, pesticide application, manure application and herbicide application. Our findings highlighted the effects of the reduction of input application rates and the consequent impacts on climate, soil, water and biodiversity. Policy makers can benefit from the outcomes of this study developing an understanding of the environmental impact of precision agriculture in order to promote and support initiatives aimed at fostering sustainable agriculture.


Sign in / Sign up

Export Citation Format

Share Document