Preparation and thermal decomposition reaction kinetics of a dysprosium(III)p-chlorobenzoate 1,10-phenanthroline complex

2007 ◽  
Vol 40 (2) ◽  
pp. 66-72 ◽  
Author(s):  
Jian Jun Zhang ◽  
Su Ling Xu ◽  
Ning Ren ◽  
Hai Yan Zhang ◽  
Liang Tian
2009 ◽  
Vol 167 (1-3) ◽  
pp. 205-208 ◽  
Author(s):  
Zhang Jiao-qiang ◽  
Gao Hong-xu ◽  
Su Li-hong ◽  
Hu Rong-zu ◽  
Zhao Feng-qi ◽  
...  

2020 ◽  
Vol 60 (1) ◽  
pp. 65-72
Author(s):  
Zhiyuan Chen ◽  
Christiaan Zeilstra ◽  
Jan Van Der Stel ◽  
Jilt Sietsma ◽  
Yongxiang Yang

2004 ◽  
Vol 113 (1-3) ◽  
pp. 67-71 ◽  
Author(s):  
Zhao Feng-qi ◽  
Chen Pei ◽  
Hu Rong-zu ◽  
Luo Yang ◽  
Zhang Zhi-zhong ◽  
...  

2019 ◽  
Vol 956 ◽  
pp. 181-191
Author(s):  
Jian Lin Xu ◽  
Bing Xue Ma ◽  
Cheng Hu Kang ◽  
Cheng Cheng Xu ◽  
Zhou Chen ◽  
...  

The thermal decomposition kinetics of polybutylene terephthalate (PBT) and flame-retardant PBT (FR-PBT) were investigated by thermogravimetric analysis at various heating rates. The kinetic parameters were determined by using Kissinger, Flynn-Wall-Ozawa and Friedman methods. The y (α) and z (α) master plots were used to identify the thermal decomposition model. The results show that the rate of residual carbon of FR-PBT is higher than that of PBT and the maximum mass loss rate of FR-PBT is lower than that of PBT. The values of activation energy of PBT (208.71 kJ/mol) and FR-PBT (244.78 kJ/mol) calculated by Kissinger method were higher than those of PBT (PBT: 195.54 kJ/mol) and FR-PBT (FR-PBT: 196.00 kJ/mol) calculated by Flynn-Wall-Ozawa method and those of PBT and FR-PBT (PBT: 199.10 kJ/mol, FR-PBT: 206.03 kJ/mol) calculated by Friedman methods. There is a common thing that the values of activation energy of FR-PBT are higher than that of PBT in different methods. The thermal decomposition reaction models of the PBT and FR-PBT can be described by Avarami-Erofeyev model (A1).


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