Kinetics of the reactions of singlet molecular oxygen (O21?g) with organic compounds in the gas phase

1973 ◽  
Vol 5 (2) ◽  
pp. 197-211 ◽  
Author(s):  
Robert E. Huie ◽  
John T. Herron
1991 ◽  
Vol 157 (1-2) ◽  
pp. 279-285 ◽  
Author(s):  
M. Seidl ◽  
J. Kaa ◽  
Max Maier

The absolute efficiencies for the vibrational excitation of molecules which quench singlet molecular oxygen have been determined from measurements of their infrared chemiluminescence and kinetics of relaxation. The systems studied were NO and CO with O 2 ( 1 ∆ g ) and NO, CO, HCl, DCl, H 2 O, D 2 O, CO 2 , N 2 O, NH 3 and C 2 H 2 with O 2 ( 1 ∑ + g ). Rate coefficients for the vibrational relaxation of a number of these molecules by molecular oxygen were also determined.


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