Relation between the alternating monomer unit sequence and the cis and trans linkage configurations at the cyclic maleic anhydride units in the copolymers of styrene and maleic anhydride prepared in carbon tetrachloride

1997 ◽  
Vol 198 (11) ◽  
pp. 3507-3516 ◽  
Author(s):  
Nguyen T. H. Ha ◽  
Kiyohisa Fujimori ◽  
Ian E. Craven
Keyword(s):  
Carbon Tetrachloride ◽  
Maleic Anhydride ◽  
Monomer Unit ◽  
Cis And Trans

E,E- and E,Z-α-phenyl-α′-acetoxyorthoquinodimethane: steric and electronic control of cycloaddition reactions

1986 ◽  
Vol 64 (4) ◽  
pp. 793-798 ◽  
Author(s):  
James L. Charlton ◽  
Mian M. Alauddin ◽  
Glenn H. Penner
Keyword(s):  
Maleic Anhydride ◽  
Electronic Properties ◽  
Dimethyl Fumarate ◽  
Diels Alder ◽  
Addition Reactions ◽  
Cycloaddition Reactions ◽  
Electronic Control ◽  
Dimethyl Maleate ◽  
Cis And Trans ◽  
Abinitio Calculations

E,E- and E,Z-α-phenyl-α′-acetoxyorthoquinodimethanes have been prepared from the corresponding cis- and trans-1-acetoxy-3-phenyl-1,3-dihydrobenzo[c]thiophene-2,2-dioxides. The regio- and diastereoselectivity of the addition reactions with dimethyl fumarate, dimethyl maleate, maleic anhydride, and methyl crotonate have been determined. Abinitio calculations have been carried out on orthoquinodimethane and its α-phenyl and α-oxy derivatives. A correlation has been made between the steric and electronic properties of the orthoquinodimethanes and the regio- and diastereoselectivity of their Diels–Alder reactions.

Photodimerization of maleic anhydride in carbon tetrachloride

1976 ◽  
Vol 17 (11) ◽  
pp. 865-868 ◽  
Author(s):  
Pierre Boule ◽  
Jacques Lemaire
Keyword(s):  
Carbon Tetrachloride ◽  
Maleic Anhydride

THE PREPARATION OF 1-ALKOXY-1,3-BUTADIENES BY PYROLYSIS OF TRIALKOXYBUTANES: II. CIS- AND TRANS-1-METHOXY-, 1-ETHOXY-, AND 1-n-PROPOXY-1,3-BUTADIENES

1950 ◽  
Vol 28b (11) ◽  
pp. 689-700 ◽  
Author(s):  
Charles G. Farmilo ◽  
R. V. V. Nicholls
Keyword(s):  
Maleic Anhydride ◽  
Catalyst Composition ◽  
Barium Silicate ◽  
Qualitative Effect ◽  
Cis And Trans

The acetals, 1,1,3-trimethoxybutane, 1,1,3-triethoxybutane, and 1,1,3-tri-n-propoxybutane have been pyrolyzed by passage over a synthetic barium silicate at various temperatures. The yields of the 1-alkoxy-1,3-butadienes isolated from the products of pyrolysis were 80, 45, and 36% respectively. A limited number of catalysts of compositions varying from BaO: 2SiO2 to BaO: 10SiO2 have been prepared, including the recommended, BaO: 5SiO2. The qualitative effect of catalyst composition of some of these silicates on the yield of 1-methoxy-1,3-butadiene has been described. trans-1-Methoxy-1,3-butadiene has been isolated and characterized by means of reactions with maleic anhydride, and a solution containing cis and trans molecules has been analyzed and shown to contain 60% cis-1-methoxy-1,3-butadiene.

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