Emulsion polymerization of styrene IV: Effect of Co(II), Ni(II), and Pb(II) on the polymerization of styrene initiated by potassium persulfate

We resolved the longtime enigma in emulsion polymerization of styrene with K2S2O8 by showing the fact that hollow polystyrene particles were successfully prepared by heat treatment in the emulsion state.

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Some Observations on the Emulsion Polymerization of Ethyl Methacrylate Initiated by Potassium Persulfate at 50°C in a Phosphate Buffer Solution of pH 6.85 and at a Low Monomer/Water Ratio

Journal of Macromolecular Science Part A - Chemistry ◽

10.1080/00222338108056797 ◽

1981 ◽

Vol 15 (8) ◽

pp. 1495-1509 ◽

Cited By ~ 2

Author(s):

U. S. Sathpathy ◽

T. K. Paul ◽

M. Banerjee ◽

R. S. Konar

Keyword(s):

Emulsion Polymerization ◽

Phosphate Buffer ◽

Phosphate Buffer Solution ◽

Potassium Persulfate ◽

Buffer Solution ◽

Ethyl Methacrylate ◽

Water Ratio

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Emulsion polymerization of vinyl chloride, potassium persulfate decomposition

Makromolekulare Chemie Macromolecular Symposia ◽

10.1002/masy.19890290127 ◽

1989 ◽

Vol 29 (1) ◽

pp. 329-337 ◽

Cited By ~ 3

Author(s):

Cecilia-Speranţa Georgescu ◽

Victor Butucea ◽

Adrians Sarbu ◽

Adrians Ionescu ◽

Ion Deaconescu ◽

...

Keyword(s):

Emulsion Polymerization ◽

Vinyl Chloride ◽

Potassium Persulfate

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Double Roles of Stabilization and Destabilization of Initiator Potassium Persulfate in Surfactant-Free Emulsion Polymerization of Styrene under Microwave Irradiation†

Langmuir ◽

10.1021/la0506630 ◽

2005 ◽

Vol 21 (18) ◽

pp. 8520-8525 ◽

Cited By ~ 23

Author(s):

To Ngai ◽

Chi Wu

Keyword(s):

Microwave Irradiation ◽

Emulsion Polymerization ◽

Potassium Persulfate

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Roles of Proton in the Formation of Particles: Soap‐free Emulsion Polymerization of Styrene using AIBN and Potassium Persulfate as Initiators

ChemistrySelect ◽

10.1002/slct.202004321 ◽

2021 ◽

Vol 6 (4) ◽

pp. 557-568

Author(s):

Xiuhang Xu ◽

Yunfei Xia ◽

Jiajia Qian ◽

Haihua Yu ◽

Yangyang Zhong ◽

...

Keyword(s):

Emulsion Polymerization ◽

Potassium Persulfate ◽

Soap Free Emulsion Polymerization

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Emulsion polymerization of styrene. II. Effect of Ag(I) and Fe(II) on the polymerization of styrene initiated by potassium persulfate

Journal of Polymer Science Polymer Chemistry Edition ◽

10.1002/pol.1982.170200318 ◽

1982 ◽

Vol 20 (3) ◽

pp. 811-815 ◽

Cited By ~ 3

Author(s):

P. Bataille ◽

B. T. Van ◽

Q. B. Pham

Keyword(s):

Emulsion Polymerization ◽

Potassium Persulfate

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Kinetics and mechanism of emulsifier-free emulsion polymerization. III. Particle growth mechanism of seeded styrene/potassium persulfate system

Journal of Polymer Science Part A Polymer Chemistry ◽

10.1002/pola.1992.080301001 ◽

1992 ◽

Vol 30 (10) ◽

pp. 2077-2083 ◽

Cited By ~ 2

Author(s):

Show-An Chen ◽

Herng-Show Chang

Keyword(s):

Emulsion Polymerization ◽

Growth Mechanism ◽

Particle Growth ◽

Potassium Persulfate ◽

Kinetics And Mechanism

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Kinetics of Impinging Streams Emulsion Polymerization of Styrene

Advanced Materials Research ◽

10.4028/www.scientific.net/amr.396-398.1402 ◽

2011 ◽

Vol 396-398 ◽

pp. 1402-1405

Author(s):

Qing Chun Fan ◽

Tian Wu ◽

Guang Wei He ◽

Fei Hong Duan

Keyword(s):

Activation Energy ◽

Apparent Activation Energy ◽

Emulsion Polymerization ◽

Potassium Persulfate ◽

Rate Of Polymerization ◽

Kinetics Of

This study is focused on the effects of the amount of initiator (potassium persulfate, KPS), monomer (styrene, St), emulsifiers, and temperature on the rate of polymerization. The experiment results show that the rate of polymerization is: Rp=K[KPS]1.374[St]1.479[S]0.875, and the apparent activation energy of polymerization is 94.64 kJ/mol.

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