Segmented polyurethanes with 4,4′-bis-(6-hydroxyhexoxy) biphenyl as chain extender. I. Synthesis and characterization of 2,4-tdi-polyurethanes

1995 ◽  
Vol 33 (9) ◽  
pp. 1523-1536 ◽  
Author(s):  
R. Mix ◽  
H. Goering ◽  
G. Schulz ◽  
E. Gründemann ◽  
J. Gähde
2014 ◽  
Vol 884-885 ◽  
pp. 247-250 ◽  
Author(s):  
Kai Sheng ◽  
Jie Lin Wang ◽  
Ying Li ◽  
Yi Han Wang ◽  
Meng Xue Xu ◽  
...  

Selecting lactam 2,6-pyridinedicarboxamide (PDCA) as the ligand and 1,4-butanediol as chain extender, we prepare polyurea polyurethane PDCA-PU; then, introduction of rare earth ion Eu3+ and small molecule ligands 1,10-phenanthroline (phen), synthesized binary and ternary polyurethane composite containing Eu3+, and comparing the fluorescence properties of the material. We investigated the thermal stability and luminescence properties of hybrids and found that the ternary hybrid materials exhibit better thermal stability and stronger emission intensity.


2011 ◽  
Vol 399-401 ◽  
pp. 359-362 ◽  
Author(s):  
Yi Chun Wang ◽  
Zheng Wei Dai ◽  
Yuan Xue

Thermo-sensitive polyurethane (TSPU) was synthesized from poly(ε-caprolactone) and 4,4’-methylenebis (phenyl isocyanate) by a two-step process with 1,4-butanediol as the chain extender. Following that, a novel temperature-sensitive material was created by the strategy of IPN from TSPU and PNIPAAm in the method of in situ polymerization. The chemical structure and thermo properties of the semi-IPN were characterized with FT-IR and DSC. The results prove that intensive inter-molecular interactions exist between TSPU and PNIPAAm chains, which have significant influence on the phase transition behaviors of the material. According to these results, the transition temperature of the semi-IPN can be adjusted in the range of 30~40 °C by controlling the composition of TSPU and the semi-IPNs.


2011 ◽  
Vol 49 (10) ◽  
pp. 2191-2198 ◽  
Author(s):  
Weiqiang Qu ◽  
Weijuan Xia ◽  
Chao Feng ◽  
Xinlin Tuo ◽  
Teng Qiu

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