Synthesis of a-shaped amphiphilic block copolymer by the combination of atom transfer radical polymerization and living anionic polymerization

In this study, a novel hyperbranched amphiphilic block copolymer was synthesized using deactivation-enhanced atom transfer radical polymerization (DE-ATRP) for smart drug delivery.

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Synthesis of Polyisoprene-b-Polystyrene Block Copolymers Bearing a Fluorescent Dye at the Junction by the Combination of Living Anionic Polymerization and Atom Transfer Radical Polymerization

Macromolecules ◽

10.1021/ma990682e ◽

2000 ◽

Vol 33 (5) ◽

pp. 1482-1486 ◽

Cited By ~ 38

Author(s):

Jiang-Dong Tong ◽

Shaoru Ni ◽

Mitchell A. Winnik

Keyword(s):

Block Copolymers ◽

Atom Transfer Radical Polymerization ◽

Radical Polymerization ◽

Anionic Polymerization ◽

Fluorescent Dye ◽

Atom Transfer ◽

Living Anionic Polymerization

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Amphiphilic block copolymer of SN38 prodrugs by atom transfer radical polymerization: Synthesis, kinetic studies and self-assembly

Journal of Controlled Release ◽

10.1016/j.jconrel.2015.05.209 ◽

2015 ◽

Vol 213 ◽

pp. e124 ◽

Cited By ~ 3

Author(s):

Xun Liu ◽

Jinqiang Wang ◽

Youqing Shen ◽

Jianbin Tang ◽

Meihua Sui

Keyword(s):

Block Copolymer ◽

Atom Transfer Radical Polymerization ◽

Radical Polymerization ◽

Self Assembly ◽

Kinetic Studies ◽

Amphiphilic Block Copolymer ◽

Atom Transfer

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Synthesis of twin-tail tadpole-shaped (cyclic polystyrene)- block-[linear poly (tert-butyl acrylate)]2 by combination of glaser coupling reaction with living anionic polymerization and atom transfer radical polymerization

Journal of Polymer Science Part A Polymer Chemistry ◽

10.1002/pola.26021 ◽

2012 ◽

Vol 50 (12) ◽

pp. 2444-2451 ◽

Cited By ~ 18

Author(s):

Bing Huang ◽

Xiaoshan Fan ◽

Guowei Wang ◽

Yannan Zhang ◽

Junlian Huang

Keyword(s):

Atom Transfer Radical Polymerization ◽

Radical Polymerization ◽

Anionic Polymerization ◽

Butyl Acrylate ◽

Coupling Reaction ◽

Atom Transfer ◽

Living Anionic Polymerization ◽

Tert Butyl ◽

Linear Poly ◽

Cyclic Polystyrene

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Preparation and self-assembly behavior of polystyrene-block-poly (dimethylaminoethyl methacrylate) amphiphilic block copolymer using atom transfer radical polymerization

eXPRESS Polymer Letters ◽

10.3144/expresspolymlett.2008.26 ◽

2008 ◽

Vol 2 (3) ◽

pp. 214-225 ◽

Cited By ~ 14

Author(s):

Y. J. Zhu ◽

Y. B. Tan ◽

X. Du

Keyword(s):

Block Copolymer ◽

Atom Transfer Radical Polymerization ◽

Radical Polymerization ◽

Self Assembly ◽

Amphiphilic Block Copolymer ◽

Atom Transfer ◽

Dimethylaminoethyl Methacrylate ◽

Assembly Behavior

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Novel fluorinated block copolymer architectures fuelled by atom transfer radical polymerization

Journal of Fluorine Chemistry ◽

10.1016/j.jfluchem.2004.11.002 ◽

2005 ◽

Vol 126 (2) ◽

pp. 241-250 ◽

Cited By ~ 43

Author(s):

Katja Jankova ◽

Søren Hvilsted

Keyword(s):

Block Copolymer ◽

Atom Transfer Radical Polymerization ◽

Radical Polymerization ◽

Atom Transfer

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ATRP Synthesis of PS-b-PtBMA and Preparation of Porous Film

Applied Mechanics and Materials ◽

10.4028/www.scientific.net/amm.364.679 ◽

2013 ◽

Vol 364 ◽

pp. 679-683

Author(s):

Chang Hao Yan ◽

Zhi Jiao Zhang ◽

Hai Yan Chen ◽

Zhong Yi Xie ◽

Ting Zhu ◽

...

Keyword(s):

Block Copolymer ◽

Atom Transfer Radical Polymerization ◽

Radical Polymerization ◽

Catalyst System ◽

Porous Film ◽

Atom Transfer ◽

H Nmr ◽

Breath Figure ◽

Breath Figure Method ◽

End Group

The polystyrene with end group of Br was synthesized by using MBrP as the initiator, CuBr/ PMDETA as the catalyst system according to atom transfer radical polymerization (ATRP). The effect of reaction temperature was studied and the system was confirmed as the active polymerization. Then PS-Br and CuBr/ PMDETA were respectively used as macroinitiator and catalyst to polymerize tBMA according to atom transfer radical polymerization (ATRP). The structure of the product was characterized by GPCFTIR1H-NMR. The amphiphilic block copolymer was obtained after hydrolysis. And the honeycomb porous film was prepared by PS-b-PMAA through using breath figure method.

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