Syntheses and characterization of carbazole based new low-band gap copolymers containing highly soluble benzimidazole derivatives for solar cell application

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Seung Ki Joo ◽  
Firat Es ◽  
Rasit Turan ◽  
Doo Won Lee

2007 ◽  
Vol 298 ◽  
pp. 777-781 ◽  
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H.-J. Schimper ◽  
Z. Kollonitsch ◽  
K. Möller ◽  
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Cheng Liao ◽  
Wolfram Jaegermann ◽  
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2021 ◽  
Vol 33 (2) ◽  
pp. 393-398
Author(s):  
Mohd Sani Sarjadi ◽  
Yap Leong Khen ◽  
Xin Lin Wong ◽  
Zuhair Jamain ◽  
Md Lutfor Rahman

Many researches have been done to obtain a low band gap and high Polymeric solar cell (PSCs) polymer either by creating new polymer or revising reported polymers from previous studies. In present work, two new copolymers were synthesized through direct arylation polymerization to produce poly(9,9-didodecylfluorene-alt-benzo[c][1,2,5]thiadiazole (P1) and poly(9,9-didodecylfluorene-altthieno[ 3,2-b]thiophene) (P2). The P1 and P2 are donor-accepter copolymers. P1 and P2 were compared to investigate its suitability to be applied in PSCs. The polymers obtained were characterized using FT-IR, NMR and UV-Vis spectroscopy. P1 shows two adsorption bands at λmax1 = 243 nm and λmax2 = 320 nm, whereas P2 also shows two adsorption bands at λmax1 = 243 nm and λmax2 = 427 nm. The optical band gap was calculated, P1 enabled band gap of 3.88 eV while P2 showed band gap of 2.91 eV. This work could be provided an insight to design and synthesize more efficient fluorene-based copolymers as active layer of PSCs in due course.


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Tasnuva Ashrafee ◽  
Krishna Aryal ◽  
Grace Rajan ◽  
Shankar Karki ◽  
Vikash Ranjan ◽  
...  

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