scholarly journals Molecular Bottle Brushes with Positioned Selenols: Extending the Toolbox of Oxidative Single Polymer Chain Folding with Conformation Analysis by Atomic Force Microscopy

2019 ◽  
Vol 58 (1) ◽  
pp. 154-162 ◽  
Author(s):  
Emmanuelle Schué ◽  
Alexey Kopyshev ◽  
Jean‐François Lutz ◽  
Hans G. Börner
Polymer ◽  
2006 ◽  
Vol 47 (7) ◽  
pp. 2505-2510 ◽  
Author(s):  
Ken Nakajima ◽  
Hiroyuki Watabe ◽  
Toshio Nishi

Langmuir ◽  
1999 ◽  
Vol 15 (8) ◽  
pp. 2799-2805 ◽  
Author(s):  
Jason E. Bemis ◽  
Boris B. Akhremitchev ◽  
Gilbert C. Walker

2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Yukari Oda ◽  
Daisuke Kawaguchi ◽  
Yuma Morimitsu ◽  
Satoru Yamamoto ◽  
Keiji Tanaka

AbstractA better understanding of the structure of polymers at solid interfaces is crucial for designing various polymer nano-composite materials from structural materials to nanomaterials for use in industry. To this end, the first step is to obtain information on how synthetic polymer chains adsorb onto a solid surface. We closely followed the trajectory of a single polymer chain on the surface as a function of temperature using atomic force microscopy. Combining the results with a full-atomistic molecular dynamics simulation revealed that the chain became more rigid on the way to reaching a pseudo-equilibrium state, accompanied by a change in its local conformation from mainly loops to trains. This information will be useful for regulating the physical properties of polymers at the interface.


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