Multiple melting behavior of poly(lactic acid) filled with modified carbon black

2009 ◽  
Vol 47 (20) ◽  
pp. 1971-1980 ◽  
Author(s):  
Zhizhong Su ◽  
Qiuying Li ◽  
Yongjun Liu ◽  
Guo-Hua Hu ◽  
Chifei Wu

2012 ◽  
Vol 111 (2) ◽  
pp. 1507-1514 ◽  
Author(s):  
Ping Song ◽  
Guangyi Chen ◽  
Zhiyong Wei ◽  
Wanxi Zhang ◽  
Jicai Liang


2014 ◽  
Vol 34 (9) ◽  
pp. 895-903 ◽  
Author(s):  
Izan R. Mustapa ◽  
Robert A. Shanks ◽  
Ing Kong

Abstract Poly(lactic acid) (PLA)-hemp-nanosilica (PHS) composites were prepared by impregnation of hemp woven fabric with PLA solution. Nanosilica was dispersed in the PLA solution to introduce a matrix reinforcing nanophase within the composite. The melting behavior of PLA composites was obtained by using differential scanning calorimetry (DSC) and modulated-temperature DSC (mT-DSC). Multiple melting which appeared in the non-isothermal heating curve showed that the temperature of a low melting peak increased when using a slower scanning rate. The incorporation of nanosilica in PLA composites affected the melting temperature (Tm) and sufficiently formed nucleation sites that promoted the growth of PLA crystals. Composites analyzed by a temperature-modulated program showed a broad exothermic peak before the melting peak in the non-reversing heat capacity and endothermic melting in the reversing heat capacity curve. This behavior was explained by a process of partial melting, recrystallization and remelting (mrr). The mT-DSC resolved that hemp fiber induced recrystallization and nanosilica acted as an effective nucleating agent, which promoted small and imperfect crystals that changed successively into more stable crystals through a melt-recrystallization process.



2001 ◽  
Vol 80 (8) ◽  
pp. 1267-1273 ◽  
Author(s):  
Yan Hui Hou ◽  
Ming Qiu Zhang ◽  
Kan Cheng Mai ◽  
Min Zhi Rong ◽  
Gang Yu ◽  
...  






Author(s):  
Jipeng Guo ◽  
Chi-Hui Tsou ◽  
Yongqi Yu ◽  
Chin-San Wu ◽  
Xuemei Zhang ◽  
...  


Polymer ◽  
2000 ◽  
Vol 41 (25) ◽  
pp. 8879-8886 ◽  
Author(s):  
S Sohn ◽  
A Alizadeh ◽  
H Marand


2010 ◽  
Vol 50 (8) ◽  
pp. 1658-1666 ◽  
Author(s):  
Zhizhong Su ◽  
Qiuying Li ◽  
Yongjun Liu ◽  
Weihong Guo ◽  
Chifei Wu


2018 ◽  
Vol 136 (13) ◽  
pp. 47273 ◽  
Author(s):  
Thaís Ferreira da Silva ◽  
Fernanda Menezes ◽  
Larissa Stieven Montagna ◽  
Ana Paula Lemes ◽  
Fabio Roberto Passador


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