A basic problem associated with the fabrication of GaP LEDs is the high dislocation density present in GaP VPE layers grown on GaP LEC substrates, which is detrimental to device performance. Most of the layer dislocations originate from loops present in the substrate that intersect the substrate surface when growth commences. This paper is concerned with an experiment designed to reduce the dislocation density in the layer by deliberately introducing lattice strains during the growth.An experimental structure was prepared comprising a substrate cut 10° off the [100] axis, onto which was grown a layer 17μm thick doped with 2 × 1019 cm-3 of N atoms, followed by a layer 30μm thick undoped. The N causes a crystallographic mismatch at the two interfaces, and it was anticipated that some of the dislocations propagating through the first layer would bend around so as to lie along the second interface.