Role of Strain-Induced Microscale Compositional Pulling on Optical Properties of High Al Content AlGaN Quantum Wells for Deep-Ultraviolet LED

A systematic study was carried out for strain-induced microscale compositional pulling effect on the structural and optical properties of high Al content AlGaN multiple quantum wells (MQWs). Investigations reveal that a large tensile strain is introduced during the epitaxial growth of AlGaN MQWs, due to the grain boundary formation, coalescence and growth. The presence of this tensile strain results in the microscale inhomogeneous compositional pulling and Ga segregation, which is further confirmed by the lower formation enthalpy of Ga atom than Al atom on AlGaN slab using first principle simulations. The strain-induced microscale compositional pulling leads to an asymmetrical feature of emission spectra and local variation in emission energy of AlGaN MQWs. Because of a stronger three-dimensional carrier localization, the area of Ga segregation shows a higher emission efficiency compared with the intrinsic area of MQWs, which is benefit for fabricating efficient AlGaN-based deep-ultraviolet light-emitting diode.

Increasing the mechanical properties of structural cast iron for machine-building parts by combined Mn – Al alloying

The object of research in this work was cast iron for machine-building parts, alloyed with Al. The possibility of improving the mechanical properties of cast iron by choosing the optimal Mn – Al combinations, depending on the carbon content in the cast iron, was determined. The study was carried out on the basis of available retrospective data of serial industrial melts by constructing the regression equation for the ultimate strength of cast iron in the three-factor space of the input variables C – Mn – Al. The optimization problem was solved by the ridge analysis method after reducing the dimension of the factor space by fixing the carbon content at three levels: C = 3 %, C = 3.3 %, and C = 3.6 %. It was found that the maximum values of the ultimate strength are achieved at the minimum level of carbon content (C = 3%) and are in the range of values close to 300 MPa. In this case, the Al content is in the range (2.4–2.6) %, and the Mn content is about 0.82 %. With an increase in the carbon content, there is a tendency to a decrease in the content of Mn and Al in the alloy, which is necessary to ensure the ultimate strength close to 300 MPa. The results of the ridge analysis of the response surface also showed that at the upper limit of the carbon content (C = 3.6%), it is not possible to reach the ultimate strength of 300 MPa in the existing range of Mn and Al variation. All solutions are verified for the following ranges of input variables C = (2.94–3.66) %, Mn = (0.5–1.1) %, Al = (1.7–2.9) %. Graphical-analytical descriptions of the optimal Mn – Al ratios are obtained, depending on the actual content of carbon in the alloy, which make it possible to purposefully select the optimal melting modes by controlling the tensile strength of the alloy

Crystallographic and optical properties of wide bandgap photovoltaic semiconductor system, Cu(Al,In)Se2

We characterized the optical and electronic properties of chalcopyrite-type Cu(Al,In)Se2, which is a candidate for wide-bandgap solar cell materials. The bandgap energy was determined from diffuse reflectance spectra. The band gap energy increased from 1.00 eV for CuInSe2 to 2.61 eV for CuAlSe2 with an increase in the Al content. The ionization energy corresponding to the energy levels of the valence band maximum (VBM) was determined using photoemission yield spectroscopy (PYS). The VBM level of the Cu(Al,In)Se2 system stayed relatively constant, but the conduction band minimum (CBM) level increased with increasing Al content. To analyze the local structures of Cu and In atoms in Cu(Al,In)Se2, Cu and In K-edge X-ray absorption fine structure (XAFS) spectra were measured at SPring-8. We discuss the crystallographic characteristics of Cu(Al,In)Se2 based on the results of the XAFS analyses and a comparison of the phase diagrams of the Cu2Se-Al2Se3, Cu2Se-In2Se3, and Cu2Se-Ga2Se3 systems.

Kinetic study on the reaction between Incoloy 825 alloy and low-fluoride slag for electroslag remelting

A kinetic model for the reactions between the low-fluoride slag CaF2–CaO–Al2O3–MgO–Li2O–TiO2 and Incoloy 825 alloy was proposed based on the two-film theory. The applicability of the model was verified to predict the variation of components in the slag–metal reaction process. The results show that the controlling step of the reaction 4[Al] + 3(TiO2) = 3[Ti] + 2(Al2O3) is the mass transfer of Al and Ti in the liquid alloy and the controlling step of the reactions 4[Al] + 3(SiO2) = 3[Si] + 2(Al2O3) and [Si] + (TiO2) = [Ti] + (SiO2) is the mass transfer of SiO2 in the molten slag. With increasing TiO2 content in the slag from 3.57% to 11.27%, the Al content in the alloy decreased whereas the Ti content increased gradually. The Si content continued to decrease during the slag–metal reaction. Soluble oxygen in the alloy reacts with Al, Ti, and Si, resulting in a decrease of the oxygen content in the alloy. The variations of TiO2 content were in good agreement with the calculated results by the kinetic model whereas the measured results of Al2O3 and SiO2 in the slag were lower than the calculated results, which is mainly due to the volatilization of fluoride.

Effect of Aluminum on Microstructure and Mechanical Properties of Weld Metal of Q960 Steel

High-strength low-alloy (HSLA) steel is used in important steel structural members because of its strength and plastic toughness. Q960 steel is HSLA steel obtained by adding an appropriate amount of alloy elements and quenching and tempering treatment on the basis of ordinary low-carbon steel. This kind of steel has strong hardenability due to the alloy elements added. Cold cracks, embrittlement and softening of the heat-affected zone easily occur after welding. In particular, the low-temperature impact toughness cannot meet the requirements and limits its use. In this paper, self-shielded welding is used to adjust the content of aluminum in flux-cored wire. The relationship between weld metal (WM) microstructure and strength and properties was studied by tensile test and impact test, and the influence mechanism of Al content on weld metal microstructure and properties was analyzed. The results show that when the content of Al is 0.21%, the impact energy at 0 °C~−60 °C is the best, the tensile strength can reach 1035 MPA and the number of pores is small. The size of inclusions in WM is mostly less than 1.0 μm Al2O3 spherical oxide. It can become the center of acicular ferrite (AF) and increase the nucleation probability. However, with the increase of Al content, large irregular AlN inclusions are produced, which reduces the tensile strength and impact energy of the welded joint.