Solid‐State Ligand‐Capped Metal Oxide Electron Transporting Layer for Efficient and Stable Fullerene‐Free Perovskite Solar Cells

Solar RRL ◽  
2021 ◽  
Author(s):  
Shih-Han Huang ◽  
Yen-Chi Wang ◽  
Kai-Chi Hsiao ◽  
Pei-Huan Lee ◽  
Hsueh-Chung Liao ◽  
...  
Coatings ◽  
2020 ◽  
Vol 10 (1) ◽  
pp. 46 ◽  
Author(s):  
Gang Lu ◽  
Xuhui Wang ◽  
Juan Du ◽  
Min Zhang ◽  
Yali Gao ◽  
...  

Perovskite solar cells have gained increasing interest in recent times owing to the rapidly enlarged device efficiency and tunable optoelectronic properties in various applications. In perovskite solar cells, interface engineering plays an important role in determining the final device efficiency and stability. In this study, we adopted TiCl4 treatment to reduce the surface roughness of the metal oxide layer and improve the perovskite film quality to obtain better device performance. After proper TiCl4 treatment, the efficiencies of TiCl4–TiO2- and TiCl4–ZnO-based devices were significantly enhanced up to 16.5% and 17.0%, respectively, compared with those based on pristine TiO2 and ZnO (13.2% and 10.2%, respectively).


Author(s):  
Selina Olthof ◽  
Kai Brinkmann ◽  
Ting Hu ◽  
Klaus Meerholz ◽  
Thoams Riedl

Rare Metals ◽  
2021 ◽  
Author(s):  
Jia-Xing Song ◽  
Xin-Xing Yin ◽  
Zai-Fang Li ◽  
Yao-Wen Li

Abstract As a promising photovoltaic technology, perovskite solar cells (pero-SCs) have developed rapidly over the past few years and the highest power conversion efficiency is beyond 25%. Nowadays, the planar structure is universally popular in pero-SCs due to the simple processing technology and low-temperature preparation. Electron transport layer (ETL) is verified to play a vital role in the device performance of planar pero-SCs. Particularly, the metal oxide (MO) ETL with low-cost, superb versatility, and excellent optoelectronic properties has been widely studied. This review mainly focuses on recent developments in the use of low-temperature-processed MO ETLs for planar pero-SCs. The optical and electronic properties of widely used MO materials of TiO2, ZnO, and SnO2, as well as the optimizations of these MO ETLs are briefly introduced. The commonly used methods for depositing MO ETLs are also discussed. Then, the applications of different MO ETLs on pero-SCs are reviewed. Finally, the challenge and future research of MO-based ETLs toward practical application of efficient planar pero-SCs are proposed. Graphical abstract


Coatings ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 404
Author(s):  
Abdul Sami ◽  
Arsalan Ansari ◽  
Muhammad Dawood Idrees ◽  
Muhammad Musharraf Alam ◽  
Junaid Imtiaz

Perovskite inorganic-organic solar cells are fabricated as a sandwich structure of mesostructured TiO2 as electron transport layer (ETL), CH3NH3PbI3 as active material layer (AML), and Spiro-OMeTAD as hole transport layer (HTL). The crystallinity, structural morphology, and thickness of TiO2 layer play a crucial role to improve the overall device performance. The randomly distributed one dimensional (1D) TiO2 nanowires (TNWs) provide excellent light trapping with open voids for active filling of visible light absorber compared to bulk TiO2. Solid-state photovoltaic devices based on randomly distributed TNWs and CH3NH3PbI3 are fabricated with high open circuit voltage Voc of 0.91 V, with conversion efficiency (CE) of 7.4%. Mott-Schottky analysis leads to very high built-in potential (Vbi) ranging from 0.89 to 0.96 V which indicate that there is no depletion layer voltage modulation in the perovskite solar cells fabricated with TNWs of different lengths. Moreover, finite-difference time-domain (FDTD) analysis revealed larger fraction of photo-generated charges due to light trapping and distribution due to field convergence via guided modes, and improved light trapping capability at the interface of TNWs/CH3NH3PbI3 compared to bulk TiO2.


Author(s):  
Kobra Valadi ◽  
Saideh Gharibi ◽  
Reza Taheri-Ledari ◽  
Seckin Akin ◽  
Ali Maleki ◽  
...  

2021 ◽  
pp. 139012
Author(s):  
Kanyaporn Thubthong ◽  
Pisist Khumnorkeaw ◽  
Anusit Kaewprajak ◽  
Khathawut Lohawet ◽  
Wiyada Saennawa ◽  
...  

Solar Energy ◽  
2021 ◽  
Vol 228 ◽  
pp. 253-262
Author(s):  
Razieh Keshtmand ◽  
Mohammad Reza Zamani-Meymian ◽  
Fateme Mohamadkhani ◽  
Nima Taghavinia

2018 ◽  
Vol 10 (48) ◽  
pp. 41312-41317 ◽  
Author(s):  
George C. Wilkes ◽  
Xiaoyu Deng ◽  
Joshua J. Choi ◽  
Mool C. Gupta

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