Effect of Al2O3, MgO, and CaO/SiO2on Viscosity of High Alumina Blast Furnace Slag

2015 ◽  
Vol 87 (2) ◽  
pp. 241-249 ◽  
Author(s):  
Lu Yao ◽  
Shan Ren ◽  
Xiaoqing Wang ◽  
Qingcai Liu ◽  
Lingyan Dong ◽  
...  
2016 ◽  
Vol 79 ◽  
pp. 257-264 ◽  
Author(s):  
Bingqiang Han ◽  
Peng Wang ◽  
Changming Ke ◽  
Wen Yan ◽  
Yaowu Wei ◽  
...  

2018 ◽  
Vol 115 (5) ◽  
pp. 502
Author(s):  
Trinath Talapaneni ◽  
Natraj Yedla ◽  
Smarajit Sarkar

In the current paper, we have determined the desulfurization ability of a CaO–MgO–SiO2–Al2O3 slag system using slag-metal equilibrium technique. The chemical composition of slag samples consists of Al2O3 in the range of 25–30 wt%, CaO/SiO2 ratio (0.8–1.6) and MgO (8–16 wt%). All the experiments are conducted at a temperature of 1773 K. The sulphur content in the slag as well as in metal after desulfurization reaction is analyzed using XRF (X-ray Fluorescence Spectroscopy) for calculating sulphur partition ratio (LS) of the slags. The influence of Al2O3, CaO/SiO2 ratio and MgO content on LS have been studied. It is observed that LS increase with an increase in CaO/SiO2 ratio and MgO content, but it reduces as the Al2O3 content increase in slag. Also, the amount of bridge oxygen ([BO]) represented by (O0) decreases with increase in basicity and MgO content. However, O0 increases with increase in Al2O3. It is witnessed that the experimental values closely fit with the values obtained from corrected optical basicity model.


Crystals ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 910
Author(s):  
Yongchun Guo ◽  
Fengman Shen ◽  
Haiyan Zheng ◽  
Shuo Wang ◽  
Xin Jiang ◽  
...  

With the consumption of high-quality iron ore resources, the grade of iron ore raw used in the iron making process has gradually decreased. The high aluminum raw materials has led to an increase in the Al2O3 content in the blast furnace slag, which has affected the normal operation of the blast furnace. The activity of the components involved in the desulfurization reaction is an important factor affecting the desulfurization process. In this paper, the effects of B(w(CaO)/w(SiO2)) and w(MgO)/w(Al2O3) on the desulfurization ability of a CaO-SiO2-MgO-Al2O3 quaternary blast furnace slag system were studied by using a double-layer graphite crucible to simulate the process of molten iron dropping through the slag at 1773 K. The desulfurization reaction mechanism of high alumina blast furnace slag is explained from the aspects of slag structure and component activity, which provides a theoretical basis for the reasonable selection of a slag making system under the condition of a high alumina content. The effects of different B and w(MgO)/w(Al2O3) on the slag structure 2343 analyzed by Fourier transform infrared spectroscopy (FT-IR). The results show that when w(MgO)/w(Al2O3) = 0.50 and w(Al2O3) = 20%, the desulfurization ability and MgO activity of slag increased with the increase of B; when w(Al2O3) = 20% and B = 1.30, the desulfurization ability and MgO activity of the slag increased with the increase of w(MgO)/w(Al2O3). The FT-IR analysis showed that with the increase of B or w(MgO)/w(Al2O3), the dissociated free oxygen ions (O2-) in the slag increased, and the dissociated free oxygen ions (O2-) interacted with the bridging oxygen (O0) of silicate, which made the complex Si-O structure in the slag gradually depolymerize and increase the desulfurization ability.


◽  
2016 ◽  
Author(s):  
Shohei Kimura ◽  
◽  
Yoshihito Kuroiwa ◽  
Hideaki Nakayama ◽  
◽  
...  

2017 ◽  
Vol 2017 ◽  
pp. 1-6 ◽  
Author(s):  
Lingtao Bian ◽  
Yanhong Gao

The effect of Al2O3, CaO/SiO2, and B2O3 on the viscosity of high alumina and medium titania blast furnace slag was analyzed. An increase in CaO/SiO2 ratio from 1.14 to 1.44 resulted in higher slag viscosity and break point temperature. They also increased with increasing Al2O3 content but decreased with adding B2O3 and Al2O3 simultaneously at a fixed CaO/SiO2 ratio of 1.14, which suggested that the effect of B2O3 on viscosity and break point temperature is predominant compared to Al2O3. Apparent activation energies of CaO–SiO2–MgO–Al2O3–TiO2–B2O3 slag were found to be between 74 and 169 kJ/mol.


Crystals ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 1279
Author(s):  
Sundaravadivelu Karthik ◽  
Kaliyaperumal Saravana Raja Mohan

In recent decades, geopolymer concrete (GPC) has been extensively researched as a potential substitute sustainable building material that may reduce CO2 emissions due to its utilization of industrial by-products. Fly ash (FA) and ground-granulated blast-furnace slag (GGBFS) are preferred geopolymer raw materials due to their obtainability and high alumina and silica concentrations. GGBFS-FA based GPC offers a clean and sustainable development technology alternative. In this study, the Taguchi method was used to optimize the mixed proportions of geopolymer concrete to achieve desired strength criteria. Four factors and four levels were considered: binder content, including four combinations of FA and GGFBS dosage, dosage of superplasticizer (0.5, 1.0, 1.5 and 2%), Na2SiO3/NaOH ratio (1.5, 2.0, 2.5 and 3), and molarity (6, 8, 10 and 12). Using these ingredients and factors, the effect of compressive strength was examined. The Taguchi approach using an L16 orthogonal array was employed to find the optimum condition of every factor while limiting the number of experiments. The findings indicated that the optimum synthesis conditions for maximum compressive strength obtained from the binder comprised 45% of FA, 45% of GGBFS and 10% of silica fume, 1.5% dosage of superplasticizer, Na2SiO3/NaOH ratio = 1.5, and 12 molar contents.


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