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2022 ◽  
Vol 119 (1) ◽  
pp. 106
Author(s):  
Mei Yang ◽  
Shuang Li ◽  
Xianju Zhang ◽  
Honglang Yang ◽  
Liping Nie ◽  
...  

Titanium alloy is an important metal material with excellent specific strength, which is widely used in aerospace field, nuclear industry, chemical medicine, and military industry. In order to investigate the connection conditions of TC4 titanium alloy and 316L stainless steel at different temperatures, the braze welding measurement with Ti57Zr13Cu21Ni9 filler metal was conducted in vacuum. The microstructure, morphology and phase of the joint were characterized by SEM (scanning electron microscope), EDS (Energy Dispersive Spectrometer) and XRD (X-ray diffraction), respectively. Microhardness and shear strength of the joint at room temperature and the bonding mechanism of TC4 and 316L were also investigated. The obtained results revealed that the main phases in the diffusion layer were Ti-based solid solution and Ti-Fe (TiFe and TiFe2) intermetallic compoundsands (IMCs) the center of the braze was mainly composed of Ti-Fe IMCs, (Ti, Zr)2(Ni, Cu), Ti-based solid solution. Additionally, the increase of brazing temperature firstly increased and then decreased the average shear strength with the maximum value of 133.9 MPa at 960 °C.


2022 ◽  
Vol 119 (1) ◽  
pp. 105
Author(s):  
Rong Zhu ◽  
Hailin Long ◽  
Haoyu Li ◽  
Huimin Xie ◽  
Shaohua Yin ◽  
...  

In this work, the alkaline refining of arsenic in crude lead was studied with a mixture of sodium hydroxide and sodium carbonate as alkaline refining agents. Taking the arsenic removal rate as the research object, the effects of reaction temperature, holding time, Na2CO3:NaOH, the dosage of refining agent were investigated. The arsenic removal rate is 79.09% under the optimum experimental conditions as follows: reaction temperature 823 K, holding time 60 min, Na2CO3:NaOH 1:4, refining agent dosage 10%. The oxidation purification mechanism of arsenic was studied by XPS, SEM-EDS, XRD and FT-IR. The results show that arsenic in the crude lead is gradually oxidized by oxygen and lead oxide during arsenic removal process, and the arsenic trioxide is eventually converted into sodium arsenate (Na3AsO4) and lead arsenate (Pb2As2O7) in the slag.


2021 ◽  
Vol 119 (1) ◽  
pp. 104
Author(s):  
Guomin Han ◽  
Hongbo Li ◽  
Yujin Liu ◽  
Jie Zhang ◽  
Ning Kong ◽  
...  

In tandem cold rolling, the control of the temperature of high-grade non-oriented silicon steel is a difficult problem for its large deformation resistance and the preheating procedure before rolling. And it is complicated to calculate the total temperature rise of rolling deformation zone due to the comprehensive influence of the plastic deformation heat, the friction heat and the contact heat loss. So, to precisely calculate the total temperature rise, firstly, based on the four classical cold rolling force formulas, the initial total temperature rise calculation models are established correspondingly by theoretically analyzing the temperature rise of deformation heat, the temperature rise of friction heat and the temperature drop of contact heat loss; then, the model based on the improved Lian rolling force formula is adopted, which leads to calculated best matching the measured temperature; finally, considering the complex formula calculation of the initial model, based on the influences of different rolling parameters on the total temperature rise, a simplified model for convenient calculation is proposed by the nonlinear regression analysis of the initial model calculation results and main rolling parameters, which is convenient for the actual application by the field technicians.


2021 ◽  
Vol 119 (1) ◽  
pp. 101
Author(s):  
Yaqiong Li ◽  
Yunlong Yu ◽  
Lifeng Zhang ◽  
Zhengtao Li

The interfacial reactions between impurities (Al and Ti) and slag onset of Si purification by 51 mol% SiO2–34 mol% CaO–15 mol% MgO slag addition were studied to enhance impurity removal efficiency from Si. The Al distribution behavior at the Si/Slag interface was investigated; a short reaction time (10 s) resulted in the formation of successive SiO2–CaO–MgO–Al2O3 layers in the slag with a thickness of 10 µm; increasing the reaction time (60 s) resulted in the entire ternary slag being changed into SiO2–CaO–MgO–Al2O3 quaternary slag due to the diffusion of Al2O3. It was shown that the highest impurity removal rate of Al could be achieved at the onset of the slag refining process. Based on the Ti distribution at the Si/slag interface, the slag refinement with 51 mol% SiO2–34 mol% CaO–15 mol% MgO had no effect on Ti removal.


2021 ◽  
Vol 119 (1) ◽  
pp. 102
Author(s):  
Hebin Wang ◽  
Da Hong ◽  
Longgang Hou ◽  
Li Shen ◽  
Ping Ou ◽  
...  

The microstructure and properties of niobium-containing AISI M3:2 high speed steels (HSSs) fabricated by spray forming and traditional casting have been investigated. The results show that fine and uniformly-distributed grains without macrosegregation appeared in the as-deposited HSSs that differ from those of as-cast HSSs. Nb mostly appears in primary MC carbides, whereas it contributes less to the formation of M6C carbides. The high stabilization of Nb-rich MC carbides can pin the grain boundaries during high-temperature austenitizing process, thus conferring a fine grains and raising the content of dissolved alloying elements. Enhanced precipitation strengthening and fine dispersion of NbC carbides throughout the matrix contribute to the high hardness and red hardness of Nb-containing HSS.


2021 ◽  
Vol 119 (1) ◽  
pp. 103
Author(s):  
Tingsong Yang ◽  
Yingwei Wang ◽  
Haijun Wang ◽  
Yang Hai ◽  
Fengshan Du

Roll profile electromagnetic control technology (RPECT) is a new strip flatness control technology that changes roll gap shape by controlling the roll profiles of electromagnetic control rolls (ECRs). To address the randomness of the flatness defect locations, this paper proposes an external adjustment method for RPECT roll profiles based on the segmented cooling principle. Based on the layout of the cooling areas and electromagnetic sticks, an electromagnetic-thermal-structural coupled model is established to analyse roll profile variations. The results show that symmetrically changing the cooling intensities of the different cooling areas can increase or decrease the roll crown of the ECR, while asymmetrically changing the cooling intensities of the different cooling areas can change the position of the maximum bulging point of the ECR. Variations in the component cooling ratio coefficient impact the effects of different cooling strategies, which needs to be considered when selecting the cooling strategy configuration scheme. Compared the maximum bulging values, radial temperature gradients and axial temperature gradients of different electromagnetic stick (ES) structures, the regulation law reverses when the length of the ES is too small, and the variation of the law is very small. Therefore, different ES structures have different segmented cooling regulation characteristics.


2021 ◽  
Vol 118 (4) ◽  
pp. 404
Author(s):  
Siddhartha Sankar Mandal ◽  
Dipak Kumar Mondal ◽  
Karuna Sindhu Ghosh

To destabilize as-cast microstructure of 20 wt.% chromium white iron, cyclic annealing involving repeated austenitization for short duration of 0.6 h at 900, 950, 1000, 1050 and 1100 °C followed by forced air cooling is conducted as an alternative to continuous annealing requiring austenitization for longer period of 4–6 h at the said temperatures followed by furnace cooling. Continuous austenitization destabilizes the austenite matrix through precipitation of secondary carbides and transforms the alloy depleted austenite to pearlite on furnace cooling, thereby reducing the as-cast hardness from HV 669 to HV466. In contrast, repeated austenitization not only destabilizes the austenite matrix through precipitation of secondary carbides followed by its transformation to martensite on forced air cooling, but also causes disintegration of longer eutectic carbides to shorter segments with subsequent increase in hardness to as high as HV 890. Notched impact toughness after both continuous and cyclic annealing remains uniformly at 12.0 J as compared to as-cast value of 6.0 J. Besides, an unexpected rise in abrasive wear resistance after cyclic annealing treatment makes the alloy superior than that obtained by continuous annealing treatment as practiced in industries.


2021 ◽  
Vol 118 (2) ◽  
pp. 209
Author(s):  
Nan Li ◽  
Feng Wang ◽  
Wei Zhang

In view of the carbon-containing composite pellets direct reduction process in rotary hearth furnace, a mathematical model coupling heterogeneous chemical reaction kinetics, heat and mass transfer of this process was established. The effects of furnace temperature (from 1273.15 K to 1673.15 K) and pellet radius (from 6 mm to 16 mm) on the direct reduction of carbon-containing composite pellets were studied by adopting computational fluid dynamics software. The pellet temperature and composition changes under different operating conditions were analyzed. CO and CO2 fluxes, heat fluxes on the pellet surface were especially studied. Total heat absorption by the pellet, CO and CO2 overflow from the pellet surface together with pellet degree of metallization (DOM) and zinc removal rate (ZRR) were calculated. Results show that with the increasing of furnace temperature or the decreasing of the pellet radius, the temperature difference between pellet surface and its center and the final DOM, ZRR increased. The larger the pellet radius, the smaller the heat absorption, also the smaller CO and CO2 overflow. But heat absorption and CO overflow per unit volume are higher. There is an optimal pellet radius with high CO utilization efficiency. Pellet porosity decreases at first and then increases with reducing time. It is also found that effective thermal conductivity is a major factor limiting the pellets temperature increasing. The reduction sequence of the pellets is Fe2O3→Fe3O4→FeO→Fe.


2021 ◽  
Vol 118 (6) ◽  
pp. 606
Author(s):  
Nandish Girishbhai Soni ◽  
Akash Ganesh Mahajan ◽  
Kaustubh Ramesh Kambale ◽  
Sandeep Prabhakar Butee

Fabrication with the in-situ formation of W2C reinforced medium carbon steel (MCS) MMC’s was attempted using W or WO3 and graphite addition to steel. The P/M route comprising milling, compaction and sintering at 1050 °C and 1120 °C respectively in 90% N2 + 10% H2 atmosphere was adopted. Both SEM and BET studies revealed the particle size to be around 100, 7 and 40 µm for MCS, W and WO3, respectively. A complete conversion of tungsten into tungsten semicarbide (W2C) was noted in XRD for the tungsten additions of ∼6, 9 and 12 wt.% with stoichiometrically balanced C (graphite) addition of 0, 0.2 and 0.4 wt.%. However, WO3 + C addition (balanced as above) revealed the partial conversion of WO3 to W2C. The peaks of Fe3C were observed only for MCS + W + C samples and not for MCS + WO3 + C samples in XRD. In SEM, the WO3 phase appeared porous and partially converted, whereas, W2C phase was dense. Sintered density improved for the addition of W, whereas it monotonically reduced for WO3 addition to MCS + C samples. Higher hardness, compressive strength, and wear resistance was noted for W addition than WO3 to MCS+C samples.


2021 ◽  
Vol 118 (6) ◽  
pp. 605
Author(s):  
Qingdang Meng ◽  
Gaocao Yu ◽  
Xueying Huang ◽  
Honglei Sun ◽  
Jun Zhao

The straightness is a critical quality parameter of metal profiles, and straightening is a necessary process in metal profile production. Due to the limitations of the existing straightening methods, the straightening process by reciprocating bending for metal profiles is proposed. The curvature is unified by multiple reciprocating bending, and then the straightening is completed by reverse bending. The process has the advantages of high straightening efficiency, flexibility, and wide straightening range. In order to verify the feasibility of the process, numerical simulation and physical experiment are carried out with the rectangular section profile with “C” shape and “S” shape. The results show the profiles of different shapes are unified into arcs of the same size after multiple reciprocating bending. In addition, the smaller the elastic area ratio (ratio of elastic deformation to overall deformation) is, the better the effect of unification curvature is. The residual deflection is basically the same after straightening, and straightness is within 0.1%.


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